ABSTRACT

Vaporization enthalpies for methyl myristoleate (methyl Z 9-tetradecenonate), methyl lO-pentadecenoate, methyl palmitoleate (methyl Z 9- hexadecenoate), methyl Z lO-heptadecenoate, methyl oleate (methyl Z 9-octadecenoate), methyllinoleate (methyl Z,Z 9,12-octadecadienoate), methyllinolenate (methyl Z,Z,Z 9,12, 15-octadecatrienoate), methyl Z ll-eicosenoate, methyl Z,Z 11,14-eicosadienoate, methyl Z,Z,Z 11,14, 17- eicosatrieneoate, methyl arachidonate (methyl Z,Z,Z,Z 5,8,1l,14-eicosatetraeneoate), methyl Z,Z,Z,Z,Z 5,8, 11,14,17-eicosapentaeneoate, methyl erucate (methyl Z 13-docosaneoate), methyl Z,Z 13,16-docosadienoate, methyl Z,Z,Z,Z,Z,Z 4,7, 10,13, 16,19-docosahexaenoate and methyl nervonate (methy1Z 15-tetracosenoate) are evaluated at T= 298.15 and vapor pressures are evaluated over the temperature range T = 298.15-450 K by correlation gas chromatography. The results are generated by an interpolative process using literature values for the saturated fatty acid methyl esters (FAMEs) from methyl decanoate to methyl tetracosanoate, exclusive of methyl nonadecanoate, heneicosanoate and tricosanoate, as standards. Relationships for calculating vapor pressures for all of the compounds studied from T=298.15 to 450K are provided.

Compounds

#	Formula	Name
1	C13H26O2	methyl dodecanoate
2	C14H28O2	methyl tridecanoate
3	C15H30O2	methyl tetradecanoate
4	C15H28O2	cis-9-tetradecenoic acid, methyl ester
5	C16H32O2	methyl pentadecanoate
6	C16H30O2	methyl cis 10-pentadecenoate
7	C17H34O2	methyl hexadecanoate
8	C17H32O2	methyl (Z)-9-hexadecenoate
9	C18H36O2	methyl heptadecanoate
10	C18H34O2	methyl cis-10-heptadecenoate
11	C19H38O2	methyl octadecanoate
12	C19H36O2	methyl cis-9-octadecenoate
13	C19H34O2	methyl (Z,Z)-9,12-octadecadienate
14	C19H32O2	methyl (Z,Z,Z)-9,12,15-octadecatrienoate
15	C21H42O2	methyl eicosanoate
16	C21H40O2	methyl cis-11-eicosenoate
17	C21H38O2	methyl Z,Z 11,14-eicosadienoate
18	C21H34O2	5,8,11,14-eicosatetraenoic acid, methyl ester, (all-Z)-
19	C21H36O2	methyl Z,Z,Z 11,14,17-eicosatrieneoate
20	C23H46O2	methyl docosanoate
21	C21H32O2	methyl Z,Z,Z,Z,Z 5,8,11,14,17-eicosapentaeneoate
22	C23H44O2	methyl (Z)-13-docosenoate
23	C23H42O2	methyl Z,Z 13,16-docosadienoate
24	C25H50O2	methyl tetracosanoate
25	C25H48O2	(Z)-methyl 15-tetracosenate
26	C23H34O2	methyl Z,Z,Z,Z,Z,Z 4,7,10,13,16,19-docosahexaeneoate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	2	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	3	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	4	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	5	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	6	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	7	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	8	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	9	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	10	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	10	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	11	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	12	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	12	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	13	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	13	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	14	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	14	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	15	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	16	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	16	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	17	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	17	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	18	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	18	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	correlation gas chromatography	4
POMD	19	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	19	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	20	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	21	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	21	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	22	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	22	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	23	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	23	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	24	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	25	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	25	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4
POMD	26	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromatography	1
POMD	26	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Correlation Gas Chromotography	4

Thermodynamics Research Center / ThermoML | Thermochimica Acta

the vaporization enthaplies and vapor pressures of a series of unstaurated fatty acid methyl esters by correlation gas chromatography

Lipkind, D.[Dmitry], Kapustin, Y.[Yaroslav], Umnahanant, P.[Patamaporn], Chickos, J. S.[James S.]

ABSTRACT