Thermodynamics Research Center / ThermoML | Thermochimica Acta

Thermal conductivity of ammonia borane complex and its composites with aluminum powder

Mohajeri, N.[Nahid], T-Raissi, A.[Ali], Ramasamy, K. K.[Karthikeyan K.]
Thermochim. Acta 2007, 452, 1, 28-30
ABSTRACT
The thermal conductivity of ammonia borane (AB) complex, in the temperature range of 300 420 K, was measured experimentally using ASTM method E 1225. At 300 K, the thermal conductivity of pure AB was found to be approximately 15 W/m-K. A composite pellet prepared by mixing 10 wt% aluminum powder with AB had a thermal conductivity that was a factor of 4 higher than that of pure AB complex. The extent of the pyrolytic weight loss for AB/Al composite and pure AB complex was 25.4% and 33.9%, respectively indicating comparatively lower levels of volatile species evolved as impurities (e.g. monomeric aminoborane, borazine, diborane, etc.) in the product hydrogen.
Compounds
# Formula Name
1 BH6N ammonia borane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Crystal
  • Temperature, K; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Coaxial cylinder method
  • 1