Thermodynamics Research Center / ThermoML | Thermochimica Acta

ABSTRACT

Liquid liquid equilibrium data for mixtures of (ethylene carbonate + benzene + cyclohexane) at temperatures 303.15 and 313.15K and (ethylene carbonate + BTX + cyclohexane) at temperature 313.15K are reported, where the BTX is benzene, toluene and m-xylene. The compositions of liquid phases at equilibrium were determined by gas liquid chromatography. The selectivity factors and partition coefficients of ethylene carbonate for the extraction of benzene, toluene and m-xylene from (ethylene carbonate + BTX + cyclohexane) are calculated and presented. The obtained results are compared with the selectivity factors and partition coefficients of ethylene carbonate for the extraction of benzene from (ethylene carbonate + benzene + cyclohexane). The liquid liquid equilibrium data were correlated with the UNIQUAC and NRTL activity coefficient models. The phase diagrams for the studied mixtures are presented and the correlated tie line results have been compared with the experimental data. The comparisons indicate the applicability of the UNIQUAC and NRTL activity coefficients model for liquid liquid equilibrium calculations of the studied mixtures. The tie line data of the studied mixtures also were correlated using the Hand method.