Thermodynamics Research Center / ThermoML | Thermochimica Acta

Thermodynamic investigation of the moderately dilute liquid Bi Fe Sb alloys

Boa, D., Hassam, S., Kotchi, K. P., Rogez, J.
Thermochim. Acta 2006, 444, 1, 86-90
ABSTRACT
The molar enthalpies of formation of liquid ternary Bi Fe Sb alloys have been determined at 1065K by direct reaction calorimetry using the drop method. Measurements were performed along two sections: XBi/XSb = 1/9 and 1/4. The experimental calorimetric data and estimated values with a Redlich-Kister formulation are compared.
Compounds
# Formula Name
1 Fe iron
2 Bi bismuth
3 Sb antimony
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Drop calorimetry
  • 35
  • POMD
  • 1
  • 3
  • 2
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Drop calorimetry
  • 35