Thermodynamics Research Center / ThermoML | Thermochimica Acta

Excess molar enthalpies of methylformate + (1-propanol, 2-propanol, 1-butanol, 2-butanol and 1-pentanol) at T = 298.15 K, p = (5.0, 10.0)MPa, and methylformate + 1-propanol at T = 333.15 K, p = 10.0MPa

Yan, W.[Weidong], Dong, H.[Hong], Zhang, R.[Rui], Li, S.[Shengying]
Thermochim. Acta 2006, 443, 1, 125-128
ABSTRACT
Ahigh pressure flow-mixing isothermal calorimeter is used to determine the excess molar enthalpies of methylformate + (1-propanol, 2-propanol, 1-butanol, 2-butanol and 1-pentanol) at T = 298.15K and p = (5.0, 10.0)MPa, and methylformate + 1-propanol at T = 333.15K and p = 10.0MPa. The Redlich Kister equation is fit to the experimental results.
Compounds
# Formula Name
1 C2H4O2 methyl methanoate
2 C3H8O propan-1-ol
3 C3H8O propan-2-ol
4 C4H10O butan-1-ol
5 C4H10O butan-2-ol
6 C5H12O pentan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Flow calorimetry
  • 57
  • POMD
  • 3
  • 1
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Flow calorimetry
  • 38
  • POMD
  • 4
  • 1
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Flow calorimetry
  • 38
  • POMD
  • 5
  • 1
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Flow calorimetry
  • 36
  • POMD
  • 6
  • 1
  • Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Flow calorimetry
  • 38