ABSTRACT

Experimental results of excess volumes, speeds of sound and viscosities at 303.15 K are presented for the binary systems of diisopropyl ether with hexane, heptane, octane, isooctane, benzene, cyclohexane, tetralin and decalin over the entire range of composition. Isentropic compressibilities are calculated from speed of sound and density data. Speeds of sound are evaluated on the basis of Jacobson free length theory and Schaaffs collision factor theory. Further, the viscosity data was analysed on the basis of corresponding states approach and Grunberg and Nissan treatment. The experimental results are discussed in terms of molecular interactions between unlike molecules.

Compounds

#	Formula	Name
1	C6H14O	diisopropyl ether
2	C6H14	hexane
3	C7H16	heptane
4	C8H18	octane
5	C8H18	2,2,4-trimethylpentane
6	C6H6	benzene
7	C6H12	cyclohexane
8	C10H12	1,2,3,4-tetrahydronaphthalene
9	C10H18	decahydronaphthalene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	2	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	3	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	4	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	6	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	6	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	7	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	7	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	8	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	8	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	8	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	9	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	9	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Capillary tube (Ostwald; Ubbelohde) method	1
POMD	9	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	1 2	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	10
POMD	1 2	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	10
POMD	1 2	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	8
POMD	1 3	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	10
POMD	1 3	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	10
POMD	1 3	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	8
POMD	1 4	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	10
POMD	1 4	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	10
POMD	1 4	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	8
POMD	1 5	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	10
POMD	1 5	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	10
POMD	1 5	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	8
POMD	6 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	9
POMD	6 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	9
POMD	6 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	7
POMD	1 7	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	9
POMD	1 7	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	9
POMD	1 7	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	7
POMD	1 8	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	9
POMD	1 8	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	9
POMD	1 8	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	7
POMD	9 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	9
POMD	9 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	9
POMD	9 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	7

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Excess volumes, densities, speeds of sound and viscosities for the binary systems of diisopropyl ether with hydrocarbons at 303.15K

Suresh Reddy, K. V. N., Sankara Reddy, G., Krishnaiah, A.

ABSTRACT