Name: ThermoML Representation of Published Experimental Data from Thermochimica Acta (0040-6031, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Titration calorimetric, densimetric and viscosimetric measurements have been combined to study the interactions of 18-crown-6 with d-glucose and d-galactose in water. The crown ether forms a thermodynamically stable 1:1 complex with d-galactose but not with d-glucose. These observations are explained in terms of the stereochemistry of the monosaccharide molecules.

Compounds

#	Formula	Name
1	C12H24O6	1,4,7,10,13,16-hexaoxacyclooctadecane
2	C6H12O6	D-glucose
3	C6H12O6	(+)-galactose
4	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 4 1	Viscosity, Pa*s ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	23
POMD	2 4 1	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	BUOYAN	23
POMD	3 4 1	Viscosity, Pa*s ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	24
POMD	3 4 1	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	BUOYAN	24

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Selective interactions of 18-crown-6 with d-glucose and d-galactose in aqueous solutions: Titration calorimetry, densimetry, viscosimetry

Volkova, N. L.[Nadezhda L.], Parfenyuk, E. V.[Elena V.]

ABSTRACT