ABSTRACT

Viscosities ? of dilute solutions of n-propylamine, n-butylamine, di-n-butylamine, and tri-n-propylamine in tetrachloromethane, n-propylamine, n-butylamine, di-n-propylamine, di-n-butylamine, tri-n-propylamine, and tri-n-butylamine in trichloromethane at 303.15 and 313.15 K and of triethylamine in 1,4-dioxane, ethyl ethanoate, butyl ethanoate, ethyl methyl ketone, chlorobenzene, and nitrobenzene have been measured at 303.15 K. The specific viscosities and viscosity deviations ?? have been calculated. Based on Eyring's theory of absolute reaction rates, values of excess Gibbs energy of activation ?G*E of viscous flow have been determined. The results have been analyzed in terms of Herskovits and Kelly equation (J. Phys. Chem. 77 (1973) 381-388) and Nakagawa equation (J. Mol. Liq. 63 (1995) 303-316).

Compounds

#	Formula	Name
1	C3H9N	propan-1-amine
2	C4H11N	1-butanamine
3	C6H15N	dipropylamine
4	C8H19N	dibutylamine
5	C9H21N	tripropylamine
6	C12H27N	tributylamine
7	C6H15N	triethylamine
8	CCl4	tetrachloromethane
9	CHCl3	trichloromethane
10	C4H8O2	1,4-dioxane
11	C4H8O2	ethyl acetate
12	C6H12O2	butyl ethanoate
13	C4H8O	butanone
14	C6H5Cl	chlorobenzene
15	C6H5NO2	nitrobenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2:UFactor:2	2
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	8	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	9	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	2
POMD	10	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	10	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	11	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	11	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	12	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	12	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	13	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	13	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	14	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	14	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	15	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:4	1
POMD	15	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	9 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	7 10	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	7 10	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	7 11	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	7 11	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	7 12	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	7 12	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	13 7	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	13 7	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	14 7	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	14 7	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	15 7	Viscosity, Pa*s ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	10
POMD	15 7	Mass density, kg/m3 ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	VIBTUB:UFactor:4	10
POMD	8 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	8 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	8 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	8 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	8 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	8 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	8 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	8 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	9 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	9 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	16
POMD	9 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	9 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18
POMD	9 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	18
POMD	9 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	18

Thermodynamics Research Center / ThermoML | Thermochimica Acta

Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents

Oswal, S. L.[Shanti Lal], Desai, J. S., Ijardar, S. P., Malek, N. I.

ABSTRACT