Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

High pressure viscosity behaviour of tris(2-ethylhexyl) trimellitate up to 150 MPa

del Rio, Jose M. Lineira, Guimarey, Maria J.G., Comunas, Maria J.P., Fernandez, Josefa
J. Chem. Thermodyn. 2019, 138, 159-166
ABSTRACT
This article presents a study on the viscous behaviour at high pressure of a synthetic oil, tris(2-ethylhexyl) trimellitate (TOTM). This fluid is being recommended as potential industrial reference material for high viscosity-high pressure measurements. Here we report new experimental viscosity values for TOTM at temperatures from 278.15 K to 373.15 K and at pressures to 150 MPa with a maximum viscosity of 2570 mPa s. The measurements have been performed using a high pressure falling-body apparatus and a Couette rotational viscometer. The experimental values obtained in this work are included in the database of a multinational project used recently to develop a reference correlation for TOTM (Wakeham et al., 2017). The universal viscosity-pressure coefficient of this fluid has been evaluated and compared with other oils, finding that it is close to the literature values of mineral oils. Moreover, we perform an analysis of the dependency of viscosity on pressure and temperature based on the density scaling concept.
Compounds
# Formula Name
1 C33H54O6 tris(2-ethylhexyl) trimellitate
2 C30H62 2,6,10,15,19,23-hexamethyltetracosane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 20
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 20
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 48
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 32