ABSTRACT

The structure of Ba5(MnO4)3Cl is refined by the Rietveld method (space group P63/m). The heat capacities of Ba5(MnO4)3Cl apatite were measured by precision adiabatic vacuum calorimetry over the temperature range from T = (6-348) K. The experimental data were used to calculate standard thermodynamic functions, namely the heat capacity Cpdeg.(T), enthalpy Hdeg.(T) - Hdeg.(0), entropy Sdeg.(T) - Sdeg.(0) and Gibbs function Gdeg.(T) - Gdeg.(0), for the range from (0 to 350) K.

Compounds

#	Formula	Name
1	Ba5ClMn3O12	barium manganese chloride oxide (Ba5Mn3O12Cl)

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Crystal	Temperature, K; Crystal Pressure, kPa; Crystal		Crystal	X-ray diffraction	1
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Crystal	Temperature, K; Crystal	Pressure, kPa; Crystal	Crystal	Vacuum adiabatic calorimetry	41
POMD	1	Molar enthalpy, kJ/mol ; Crystal	Temperature, K; Crystal	Pressure, kPa; Crystal	Crystal	Vacuum adiabatic calorimetry	41
POMD	1	Molar entropy, J/K/mol ; Crystal	Temperature, K; Crystal	Pressure, kPa; Crystal	Crystal	Vacuum adiabatic calorimetry	41
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Crystal	Temperature, K; Crystal	Pressure, kPa; Crystal	Crystal	Vacuum adiabatic calorimetry	196

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Synthesis, structure and thermodynamic properties of Ba5(MnO4)3Cl apatite

Knyazev, A.V., Bulanov, E.N., Smirnova, N.N., Korshak, K.S., Xu, Z., Sarmini, Yu.A.

ABSTRACT