Solubility of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-diolate in (formic acid, water) and their binary solvents from 298.15 K to 333.15 K at 101.1 kPa
In this study, the solubility of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-diolate (TKX-50) in formic acid, water and mixed solvents (formic acid + water) were measured with the temperature ranging from 298.15 K to 333.15 K by using a laser dynamic monitoring technique at 101.1 kPa. The experimental data showed that the solubility of TKX-50 increase with the increasing temperature in all solvents and decrease with the decreasing proportion of formic acid in mixed solvents (formic acid + water) at constant temperature. The mole fraction solubility of TKX-50 in pure formic acid and pure water were correlated with the modified Apelblat equation and the van't Hoff equation, the mole fraction solubility in mixed solvents (formic acid + water) were correlated with the (CNIBS)/R-K equation, the Jouyban-Acree model, the Apelblat-Jouyban-Acree model, the van't Hoff-Jouyban-Acree model, the Sun model and the Ma model. The result showed that calculated values correlated by these models are consistent with the experimental data. The solubility of TKX-50 in mixed solvents (formic acid + water) will provide essential support for the further research of crystallization and spheroidization of TKX-50.
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.