Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Measurements of bubble point pressure and saturated liquid density for ((R1234yf + R290))

Zhong, Quan, Li, Huiya, Dong, Xueqiang, Zhang, Haiyang, Zhao, Yanxing, Guo, Hao, Shen, Jun, Gong, Maoqiong
J. Chem. Thermodyn. 2018, 118, 77-81
ABSTRACT
In this paper, bubble point pressures and saturated liquid densities of {2,3,3,3-Tetrafluoroprop-1-ene (R1234yf) + propane (R290)} binary mixtures were measured using a compact single-sinker densimeter. Measurements were carried out over temperatures from (255.048 to 300.135) K and mole fractions of R1234yf at (0.113, 0.217, 0.322, 0.422, 0.533, 0.625). The experimental standard uncertainties were estimated to be less than 5 mK for the temperature, 2 kPa for the pressure, 0.003 for the mole fraction and 0.02% for the density. The experimental bubble point pressures were correlated by the Peng-Robinson equation of state, while the experimental saturated liquid densities were represented with the VDNS and our modified Rackett equations. In addition, saturated liquid densities of azeotropy point at temperatures T = (253.150, 263.150, 273.150, 283.150 and 293.150) K were determined based on our previous and present work.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 50
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 50