Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Absorption performance of (CO2 + N2) gas mixtures in amino acid ionic liquids promoted N-methyldiethanolamine aqueous solutions

Fu, Dong, Feng, Xue, Zhang, Pan
J. Chem. Thermodyn. 2017, 113, 250-256
ABSTRACT
Amino acid ionic liquids (AAILs) including 1-butyl-3-methylimidazolium glycinate ([Bmim][Gly]), 1- butyl-3-methylimidazolium L-lysinate ([Bmim][Lys]) and tetramethylammonium glycinate ([N1111] [Gly]) were used to enhance the absorption of CO2 in N-methyldiethanolamine (MDEA) aqueous solutions. The mole fractions of CO2 in N2 + CO2 gas mixtures ranged from 0.2 to 1.0. The mass fractions of MDEA and AAILs respectively ranged from 0.300 to 0.400 and 0.050 to 0.100. The absorption capacity and absorption rate under series of conditions were presented and the influences of CO2 partial pressure and the types of AAILs on the absorption performance were demonstrated.
Compounds
# Formula Name
1 H2O water
2 C2H7NO 2-aminoethan-1-ol
3 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • 3
  • Mass ratio of solute to solvent - 3 ; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Volumetric method
  • 1