ABSTRACT

Densities (q) and speeds of sound (c) measurements of D( )-ribose and D(+)-xylose in (0.2, 0.4, 0.6) mol kg 1 aqueous solutions of trilithium citrate (TLC) have been carried out at different temperatures. The experimental results were used to calculate apparent molar and partial molar quantities, partial molar volumes and partial molar isentropic compression of transfer. The pair and triplet interaction coefficients are computed from transfer parameters. The partial molar expansibilities have also been calculated. The results have been interpreted in terms of prevailing interactions and structure making and breaking tendency of the solutes in aqueous solution of TLC.

Compounds

#	Formula	Name
1	C5H10O5	D-ribose
2	C5H10O5	D-xylose
3	C6H5Li3O7	trilithium citrate
4	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 3 4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 3; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Single path-length method	156
POMD	1 3 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 3; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	156
POMD	2 3 4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 3; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Single path-length method	156
POMD	2 3 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 3; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	156

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Temperature dependence of the volumetric and acoustic behaviour of aqueous mixtures of monosaccharides and trilithium citrate

Kumar, H.[Harsh], Sheetal, Behal, I.[Isha], Sharma, S.[Sanjay]

ABSTRACT