Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Density and viscosity measurements of aqueous amines at high pressures: DEA-water, DMAE-water and TEA-water mixtures

Concepcion, E. I.[Eduardo I.], Gomez-Hernandez, A.[Angel], Martin, M. C., Segovia, J. J.[Jose J.]
J. Chem. Thermodyn. 2017, 112, 227-239
ABSTRACT
In this paper, density and viscosity measurements at pressures up to 140 MPa are presented in a temperature range from (293.15 to 393.15) K for diethanolamine (DEA) + water, triethanolamine (TEA) + water and 2-dimethylaminoethanol (DMAE) + water in amine weight concentrations from 10% to 40%. Densities were measured using a vibrating tube densimeter (Anton Paar DMA HPM) with an expanded uncertainty (k = 2) less than +-0.7 kg m 3. Viscosity measurements were obtained using a falling body viscometer which was calibrated with water and dodecane. The viscosity expanded uncertainty (k = 2) ranges from +-2.5% for the highest viscosity to +-3.2% for the lowest.
Compounds
# Formula Name
1 C4H11NO2 diethanolamine
2 C6H15NO3 triethanolamine
3 C4H11NO 2-(N,N-dimethylamino)ethanol
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 480
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 256
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 16
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 480
  • POMD
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 16
  • POMD
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 256
  • POMD
  • 3
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 480
  • POMD
  • 3
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 16
  • POMD
  • 3
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 254