Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Determination of melting temperatures in hydrocarbon mixtures by differential scanning calorimetry

Oakley, J. H.[Jordan H.], Hughes, T. J.[Thomas J.], Graham, B. F.[Brendan F.], Marsh, K. N.[Kenneth N.], May, E. F.[Eric F.]
J. Chem. Thermodyn. 2017, 108, 59-70
ABSTRACT
There is a lack of consistency in the literature about how to determine the melting (liquidus) temperature in a hydrocarbon mixture from thermograms recorded by differential scanning calorimetry (DSC). This paper establishes a robust technique for determining liquidus temperatures by DSC by testing two methods detailed in the literature and assessing the potential for de-mixing to preclude repeatable measurements. Liquidus temperatures determined via the end set scanning method were found to be consistent with literature measurements of the same mixture obtained visually, and with a liquidus temperature measured for a fresh sample using the step method. In contrast, use of the thermogram s peak temperature produced inconsistent results that often could not be reasonably extrapolated to zero scan rate. The impact of any sample de-mixing that may have occurred over multiple freeze-melt cycles was negligible, as demonstrated by the consistency of the thermograms repeated at the same scan rate, and the consistency of liquidus temperatures obtained with different sample loadings into the DSC. New (solid + liquid) equilibrium results are reported for {heptane + hexadecane (C16)} and (hexane + hexadecane) binaries as well as a (hexane + para-xylene + hexadecane) ternary over a temperature range from (260.80 to 279.17) K at atmospheric pressure. Comparisons of the binary measurements against both literature data and the calculations with a property package implemented in commercial software showed deviations of less than 1 K for mixtures with C16 solute mole fractions around 0.3, and -3 K for the mixture with a C16 solute mole fraction around 0.1, due to the increasing sensitivity of the liquidus temperature on composition as the solute fraction decreases. The ternary mixture, with a C16 solute mole fraction of around 0.1, showed a deviation of -5 K, suggesting the property package does not adequately capture the interactions associated with the presence of an aromatic component.
Compounds
# Formula Name
1 C6H14 hexane
2 C8H10 1,4-dimethylbenzene
3 C16H34 hexadecane
4 C7H16 heptane
5 H2O water
6 Hg mercury
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 5
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 6
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • DTA
  • 2
  • POMD
  • 1
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • DTA
  • 2
  • POMD
  • 2
  • 1
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • DTA
  • 1