Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental study on the gaseous p.rho.Tx properties for (HFO1234yf + HC290)

Zhong, Q.[Quan], Dong, X.[Xueqiang], Zhang, H.[Haiyang], Li, H.[Huiya], Gong, M.[Maoqiong], Shen, J.[Jun], Wu, J.[Jianfeng]
J. Chem. Thermodyn. 2017, 107, 126-132
ABSTRACT
Values of gaseous p.rho.Tx were measured with a compact single-sinker densimeter for {2,3,3,3- tetrafluoroprop-1-ene (HFO1234yf) + propane (HC290)} mixtures. A total of 168 data points was obtained at temperatures from (265.460 to 300.268) K, pressure up to 0.70252 MPa, and mole fractions of HFO1234yf at (0.0906, 0.2546, 0.5830, 0.8116, and 1.0000). For the densimeter, values of the experimental standard uncertainty were less than 5 mK for the temperature, 200 Pa for the pressure, and 0.0003 for the mole fraction. When all the experimental standard uncertainties are considered, the relative uncertainty in density was estimated to be less than 0.13%. The experimental results were correlated using a truncated virial equation of state (EOS) and the Patel-Teja (PT) EOS. The virial model gives the best description of the experimental pqTx values with average absolute relative deviations of 0.080% in pressure and 0.085% in density.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 32
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 168