Phase equilibrium of (CO2 + 1-aminopropyl-3-methylimidazolium bromide + water) electrolyte system and effects of aqueous medium on CO2 solubility: Experiment and modeling
New experimental data for solubility of carbon dioxide (CO2) in the aqueous solution of 1-aminopropyl- 3-methylimidazolium bromide ([APMIm]Br) with four different water mass fractions (0.559, 0.645, 0.765 and 0.858) at T = (278.15-348.15) K with an interval of T = 10 K and p = (0.1237-6.9143) MPa were presented. The electrolyte nonrandom two-liquid (eNRTL) model was modified to be applicable for an ionic liquid (IL) aqueous solution system, by introducing an idle factor b to illustrate the association effect of IL molecules. A solution Henry fs constant for CO2 solubility in the IL aqueous solution was defined by introducing a correlative coefficient Rs .. The vapor-liquid phase equilibrium of the [APMIm]Br-H2O-CO2 ternary system was successfully calculated with the modified eNRTL model. The chemical and physical mechanisms for the ionized CO2 formation and the molecular CO2 dissolved in the solution were identified. The effects of aqueous medium on both chemical and physical dissolution of CO2 in the [APMIm]Br aqueous solution were studied, and a considerable enhancement of the solubility of CO2 with increase of the water content in the solution was observed.
Compounds
#
Formula
Name
1
C7H14BrN3
1-aminopropyl-3-methylimidazolium bromide
2
CO2
carbon dioxide
3
H2O
water
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.