Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Surface thermodynamics of DMA2P, DMA2P-MEA and DMA2P-PZ aqueous solutions

Fu, D.[Dong], Wang, L.[LeMeng], Tian, X.[XiangFeng]
J. Chem. Thermodyn. 2017, 107, 79-84
ABSTRACT
The surface tension (c) of 1-dimethylamino-2-propanol (DMA2P), DMA2P-monoethanolamine (MEA), and DMA2P-piperazine (PZ) aqueous solutions was measured by using the BZY-1 surface tension meter. The temperature ranged from 303.2 K to 323.2 K. The mass fractions of DMA2P, MEA and PZ respectively ranged from 0.30 to 0.50, 0.05 to 0.15 and 0.025 to 0.075. An equation was proposed to model the surface tension and the calculated results agreed well with the experiments. The surface thermodynamics including surface enthalpy and surface entropy were determined and their concentration dependence was analysed.
Compounds
# Formula Name
1 C5H13NO 1-(dimethylamino)-2-propanol
2 C2H7NO 2-aminoethan-1-ol
3 C4H10N2 piperazine
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 3
  • POMD
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 1
  • POMD
  • 1
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 30
  • POMD
  • 1
  • 2
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 27
  • POMD
  • 1
  • 3
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 3; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 27