2
0
2017
vat
doh
0
journal
Original
Vatascin, E.[Erika]
Dohnal, V.[Vladimir]
J. Chem. Thermodyn.
2017
2020-09-29
Thermodynamic properties of aqueous solutions of [EMIM] thiocyanate and [EMIM] dicyanamide
Thermodynamic behavior of aqueous solutions of two ionic liquids (ILs), [EMIM][SCN] and [EMIM][DCA], was thoroughly characterized. Vapor liquid equilibria (water activity), mixing enthalpy, density, and viscosity were systematically measured in the entire composition range and/or specifically in the highly dilute IL region, as a function of temperature in the range from (288.15 to 318.15) K. Pertinent information available in the literature was gathered and critically examined. Data on system energetics, measured in this work and selected from the literature, were simultaneously correlated with an NRTL-type model. Despite complicated courses of excess energetic functions, their compact, thermodynamically consistent and adequate representation was achieved and the model description was proved to provide reasonable extrapolations. Excess volumes (positive) and viscosity deviations (negative) as functions of composition and temperature were correlated with Pade approximants with T-dependent parameters yielding adequate representation of data even for the M-shaped curves encountered for the excess volume of (water + [EMIM][SCN]). The aqueous solutions of [EMIM][SCN] and [EMIM][DCA] were found to exhibit a closely similar energetic behavior. Both systems display large negative excess Gibbs energy and S-shaped excess enthalpy and excess heat capacity which are positive in the IL dilute region and change to negative and close-to-zero, respectively, as the IL content increases. The inferred excess entropy is markedly positive, reflecting vast disorganization of nano-scale structures upon mixing the ILs with water. A detailed inspection of the energetic functions of the two systems revealed consistently more positive values for [EMIM][SCN] indicating that [DCA] is slightly more hydrophilic anion than [SCN] . Comparison to [EMIM][tricyanomethanide] studied previously showed that [DCA] and [SCN] are considerably more hydrophilic than [TCM] .
Ionic liquid
Water activity
Excess thermodynamic properties
Viscosity
10.1016/j.jct.2016.12.008
106
262-275
1
InChI=1S/C6H11N2.CHNS/c1-3-8-5-4-7(2)6-8;2-1-3/h4-6H,3H2,1-2H3;3H/q+1;/p-1
VASPYXGQVWPGAB-UHFFFAOYSA-M
1-ethyl-3-methylimidazolium thiocyanate
[EMIM][SCN]
C7H11N3S
1
Commercial source
1
99.7
3
Stated by supplier
2
Dried by vacuum heating
3
0.0047
2
Karl Fischer titration
4
0.01
1
Ion chromatography
2
InChI=1S/C6H11N2.C2N3/c1-3-8-5-4-7(2)6-8;3-1-5-2-4/h4-6H,3H2,1-2H3;/q+1;-1
MKHFCTXNDRMIDR-UHFFFAOYSA-N
1-ethyl-3-methylimidazolium dicyanamide
C8H11N5
1
Commercial source
1
99
3
Stated by supplier
2
Dried by vacuum heating
3
0.0029
2
Karl Fischer titration
3
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
Fractional distillation
2
99.8
3
Estimated by the compiler
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
1124.01
6
1
1
1
293.15
5
1
1120.92
6
1
1
1
298.15
5
1
1117.85
6
1
1
1
303.15
5
1
1114.8
6
1
1
1
308.15
5
1
1111.76
6
1
1
1
313.15
5
1
1108.74
6
1
1
1
318.15
5
1
1105.73
6
1
1
2
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
0.03424
4
1
0.00073
1
293.15
5
1
0.0279
4
1
0.00059
1
298.15
5
1
0.02268
4
1
0.00048
1
303.15
5
1
0.01909
4
1
0.00041
1
308.15
5
1
0.01639
4
1
0.00035
1
313.15
5
1
0.01418
4
1
0.0003
1
318.15
5
1
0.01243
4
1
0.00026
3
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
1108.12
6
1
2.02
1
293.15
5
1
1104.77
6
1
2.02
1
298.15
5
1
1101.44
6
1
2.02
1
303.15
5
1
1098.12
6
1
2.02
1
308.15
5
1
1094.83
6
1
2.02
1
313.15
5
1
1091.54
6
1
2.02
1
318.15
5
1
1088.28
6
1
2.02
4
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
0.01998
4
1
0.00121
1
293.15
5
1
0.01693
4
1
0.00103
1
298.15
5
1
0.01454
4
1
0.00088
1
303.15
5
1
0.01263
4
1
0.00077
1
308.15
5
1
0.01105
4
1
0.00067
1
313.15
5
1
0.00976
3
1
0.00059
1
318.15
5
1
0.00869
3
1
0.00053
5
3
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
1
288.15
5
1
999.08
5
1
0.11
1
293.15
5
1
998.19
5
1
0.11
1
298.15
5
1
997.03
5
1
0.11
1
303.15
5
1
995.63
5
1
0.11
1
308.15
5
1
994.02
5
1
0.11
1
313.15
5
1
992.2
5
1
0.11
1
318.15
5
1
990.2
5
1
0.11
6
3
1
Principal objective of the work
AB
TRC
8/1/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
1
288.15
5
1
0.00113
3
1
1e-05
1
293.15
5
1
0.001
3
1
1e-05
1
298.15
5
1
0.00089
2
1
1e-05
1
303.15
5
1
0.0008
2
1
1e-05
1
308.15
5
1
0.00072
2
1
1e-05
1
313.15
5
1
0.00065
2
1
1e-05
1
318.15
5
1
0.0006
2
1
1e-05
7
3
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
(Relative) activity
chilled-mirror dew point technique
3
Liquid
Direct value, X
Pure compound
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
293.14
5
2
0.95075
5
1
0.9558
4
1
0.0387
1
298.14
5
2
0.95075
5
1
0.9565
4
1
0.0387
1
303.12
5
2
0.95075
5
1
0.9568
4
1
0.0387
1
308.13
5
2
0.95075
5
1
0.9569
4
1
0.0387
1
313.11
5
2
0.95075
5
1
0.9572
4
1
0.0387
1
318.14
5
2
0.95075
5
1
0.9565
4
1
0.0387
1
293.13
5
2
0.9122
5
1
0.9239
4
1
0.0387
1
298.14
5
2
0.9122
5
1
0.9242
4
1
0.0387
1
303.13
5
2
0.9122
5
1
0.9238
4
1
0.0387
1
308.13
5
2
0.9122
5
1
0.9223
4
1
0.0387
1
313.11
5
2
0.9122
5
1
0.9213
4
1
0.0387
1
318.13
5
2
0.9122
5
1
0.92
4
1
0.0387
1
293.15
5
2
0.79883
5
1
0.7796
4
1
0.0387
1
298.15
5
2
0.79883
5
1
0.7797
4
1
0.0387
1
303.13
5
2
0.79883
5
1
0.7781
4
1
0.0387
1
308.14
5
2
0.79883
5
1
0.7758
4
1
0.0387
1
313.12
5
2
0.79883
5
1
0.7737
4
1
0.0387
1
318.15
5
2
0.79883
5
1
0.7717
4
1
0.0387
1
293.14
5
2
0.69661
5
1
0.601
4
1
0.0387
1
298.14
5
2
0.69661
5
1
0.6001
4
1
0.0387
1
303.12
5
2
0.69661
5
1
0.5987
4
1
0.0387
1
308.12
5
2
0.69661
5
1
0.5975
4
1
0.0387
1
313.11
5
2
0.69661
5
1
0.5959
4
1
0.0387
1
318.13
5
2
0.69661
5
1
0.5946
4
1
0.0387
1
288.14
5
2
0.59853
5
1
0.4399
4
1
0.0387
1
293.12
5
2
0.59853
5
1
0.4414
4
1
0.0387
1
298.12
5
2
0.59853
5
1
0.4407
4
1
0.0387
1
303.11
5
2
0.59853
5
1
0.4402
4
1
0.0387
1
308.11
5
2
0.59853
5
1
0.4392
4
1
0.0387
1
313.09
5
2
0.59853
5
1
0.4384
4
1
0.0387
1
318.12
5
2
0.59853
5
1
0.4374
4
1
0.0387
1
288.08
5
2
0.50076
5
1
0.3061
4
1
0.0387
1
293.11
5
2
0.50076
5
1
0.3065
4
1
0.0387
1
298.12
5
2
0.50076
5
1
0.3065
4
1
0.0387
1
303.09
5
2
0.50076
5
1
0.3066
4
1
0.0387
1
308.1
5
2
0.50076
5
1
0.3062
4
1
0.0387
1
313.08
5
2
0.50076
5
1
0.3058
4
1
0.0387
1
318.11
5
2
0.50076
5
1
0.3055
4
1
0.0387
1
290.08
5
2
0.39951
5
1
0.2032
4
1
0.0387
1
293.08
5
2
0.39951
5
1
0.2036
4
1
0.0387
1
298.1
5
2
0.39951
5
1
0.2042
4
1
0.0387
1
303.06
5
2
0.39951
5
1
0.2044
4
1
0.0387
1
308.06
5
2
0.39951
5
1
0.2045
4
1
0.0387
1
313.05
5
2
0.39951
5
1
0.2046
4
1
0.0387
1
318.08
5
2
0.39951
5
1
0.2046
4
1
0.0387
1
288.11
5
2
0.25232
5
1
0.0986
3
1
0.0387
1
293.11
5
2
0.25232
5
1
0.1001
4
1
0.0387
1
298.12
5
2
0.25232
5
1
0.1
4
1
0.0387
1
303.06
5
2
0.25232
5
1
0.0996
3
1
0.0387
1
308.06
5
2
0.25232
5
1
0.0998
3
1
0.0387
1
313.02
5
2
0.25232
5
1
0.0993
3
1
0.0387
1
318.01
5
2
0.25232
5
1
0.1002
4
1
0.0387
1
290.07
5
2
0.20196
5
1
0.0706
3
1
0.0387
1
293.07
5
2
0.20196
5
1
0.0711
3
1
0.0387
1
298.07
5
2
0.20196
5
1
0.0716
3
1
0.0387
1
303.05
5
2
0.20196
5
1
0.0721
3
1
0.0387
1
308.06
5
2
0.20196
5
1
0.0724
3
1
0.0387
1
313.02
5
2
0.20196
5
1
0.0728
3
1
0.0387
1
318.07
5
2
0.20196
5
1
0.0732
3
1
0.0387
8
3
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
288.15
5
2
0.003562
4
1
0.02626
4
1
0.0014
1
288.15
5
2
0.00297
4
1
0.02232
4
1
0.00126
1
288.15
5
2
0.002377
4
1
0.01804
4
1
0.00112
1
288.15
5
2
0.001784
4
1
0.01386
4
1
0.00099
1
288.15
5
2
0.00119
4
1
0.00939
3
1
0.00086
1
288.15
5
2
0.000595
3
1
0.00475
3
1
0.00081
1
298.15
5
2
0.00356
4
1
0.02742
4
1
0.00144
1
298.15
5
2
0.002968
4
1
0.02319
4
1
0.00129
1
298.15
5
2
0.002376
4
1
0.01882
4
1
0.00114
1
298.15
5
2
0.001783
4
1
0.01434
4
1
0.001
1
298.15
5
2
0.001189
4
1
0.00972
3
1
0.00087
1
298.15
5
2
0.000595
3
1
0.00487
3
1
0.00081
1
308.15
5
2
0.00356
4
1
0.02885
4
1
0.0015
1
308.15
5
2
0.002968
4
1
0.02433
4
1
0.00133
1
308.15
5
2
0.002375
4
1
0.01969
4
1
0.00117
1
308.15
5
2
0.001783
4
1
0.01501
4
1
0.00102
1
308.15
5
2
0.001189
4
1
0.01013
4
1
0.00088
1
308.15
5
2
0.000595
3
1
0.00508
3
1
0.00082
1
318.15
5
2
0.003562
4
1
0.03036
4
1
0.00155
1
318.15
5
2
0.002969
4
1
0.02562
4
1
0.00138
1
318.15
5
2
0.002377
4
1
0.02079
4
1
0.00121
1
318.15
5
2
0.001784
4
1
0.0158
4
1
0.00105
1
318.15
5
2
0.00119
4
1
0.01063
4
1
0.0009
1
318.15
5
2
0.000595
3
1
0.0053
3
1
0.00082
9
3
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
288.15
5
2
0.003562
4
1
1002.576
7
1
0.111
1
288.15
5
2
0.00297
4
1
1002.03
7
1
0.11
1
288.15
5
2
0.002377
4
1
1001.456
7
1
0.109
1
288.15
5
2
0.001784
4
1
1000.887
7
1
0.108
1
288.15
5
2
0.00119
4
1
1000.303
7
1
0.107
1
288.15
5
2
0.000595
3
1
999.706
6
1
0.106
1
298.15
5
2
0.00356
4
1
1000.23
7
1
0.107
1
298.15
5
2
0.002968
4
1
999.724
6
1
0.109
1
298.15
5
2
0.002376
4
1
999.205
6
1
0.108
1
298.15
5
2
0.001783
4
1
998.678
6
1
0.108
1
298.15
5
2
0.001189
4
1
998.146
6
1
0.107
1
298.15
5
2
0.000595
3
1
997.593
6
1
0.107
1
308.15
5
2
0.00356
4
1
996.975
6
1
0.107
1
308.15
5
2
0.002968
4
1
996.502
6
1
0.109
1
308.15
5
2
0.002375
4
1
996.024
6
1
0.108
1
308.15
5
2
0.001783
4
1
995.543
6
1
0.108
1
308.15
5
2
0.001189
4
1
995.047
6
1
0.107
1
308.15
5
2
0.000595
3
1
994.541
6
1
0.107
1
318.15
5
2
0.003562
4
1
992.957
6
1
0.11
1
318.15
5
2
0.002969
4
1
992.518
6
1
0.11
1
318.15
5
2
0.002377
4
1
992.069
6
1
0.109
1
318.15
5
2
0.001784
4
1
991.619
6
1
0.108
1
318.15
5
2
0.00119
4
1
991.157
6
1
0.108
1
318.15
5
2
0.000595
3
1
990.684
6
1
0.108
10
3
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
288.15
5
2
0
6
1
1124.01
6
1
1
1
288.15
5
2
0.10057
5
1
1122.17
6
1
0.9
1
288.15
5
2
0.19483
5
1
1120.28
6
1
0.82
1
288.15
5
2
0.30263
5
1
1117.74
6
1
0.73
1
288.15
5
2
0.40112
5
1
1114.62
6
1
0.65
1
288.15
5
2
0.49793
5
1
1110.81
6
1
0.57
1
288.15
5
2
0.60433
5
1
1104.78
6
1
0.47
1
288.15
5
2
0.68866
5
1
1097.66
6
1
0.39
1
288.15
5
2
0.79814
5
1
1083.09
6
1
0.29
1
288.15
5
2
0.91048
5
1
1053.6
6
1
0.19
1
288.15
5
2
0.94426
5
1
1038.64
6
1
0.18
1
288.15
5
2
0.95057
5
1
1035.25
6
1
0.16
1
288.15
5
2
1
6
1
999.08
5
1
0.11
1
293.15
5
2
0
6
1
1120.92
6
1
1
1
293.15
5
2
0.10057
5
1
1119.09
6
1
0.9
1
293.15
5
2
0.19483
5
1
1117.18
6
1
0.82
1
293.15
5
2
0.30263
5
1
1114.62
6
1
0.73
1
293.15
5
2
0.40112
5
1
1111.48
6
1
0.65
1
293.15
5
2
0.49793
5
1
1107.64
6
1
0.57
1
293.15
5
2
0.60433
5
1
1101.58
6
1
0.47
1
293.15
5
2
0.68866
5
1
1094.44
6
1
0.39
1
293.15
5
2
0.79814
5
1
1079.92
6
1
0.29
1
293.15
5
2
0.91048
5
1
1050.85
6
1
0.19
1
293.15
5
2
0.94426
5
1
1036.27
6
1
0.18
1
293.15
5
2
0.95057
5
1
1032.98
6
1
0.16
1
293.15
5
2
1
6
1
998.19
5
1
0.11
1
298.15
5
2
0
6
1
1117.85
6
1
1
1
298.15
5
2
0.10057
5
1
1116.01
6
1
0.9
1
298.15
5
2
0.19483
5
1
1114.09
6
1
0.82
1
298.15
5
2
0.30263
5
1
1111.51
6
1
0.73
1
298.15
5
2
0.40112
5
1
1108.34
6
1
0.65
1
298.15
5
2
0.49793
5
1
1104.48
6
1
0.57
1
298.15
5
2
0.60433
5
1
1098.38
6
1
0.47
1
298.15
5
2
0.68866
5
1
1091.23
6
1
0.39
1
298.15
5
2
0.91048
5
1
1048.04
6
1
0.19
1
298.15
5
2
0.94426
5
1
1033.79
6
1
0.17
1
298.15
5
2
0.95057
5
1
1030.58
6
1
0.16
1
298.15
5
2
1
6
1
997.03
5
1
0.11
1
303.15
5
2
0
6
1
1114.8
6
1
1
1
303.15
5
2
0.10057
5
1
1112.95
6
1
0.9
1
303.15
5
2
0.19483
5
1
1111.01
6
1
0.82
1
303.15
5
2
0.30263
5
1
1108.41
6
1
0.72
1
303.15
5
2
0.40112
5
1
1105.22
6
1
0.65
1
303.15
5
2
0.49793
5
1
1101.33
6
1
0.57
1
303.15
5
2
0.60433
5
1
1095.19
6
1
0.47
1
303.15
5
2
0.68866
5
1
1088.01
6
1
0.39
1
303.15
5
2
0.91048
5
1
1045.18
6
1
0.19
1
303.15
5
2
0.94426
5
1
1031.22
6
1
0.17
1
303.15
5
2
0.95057
5
1
1028.1
6
1
0.16
1
303.15
5
2
1
6
1
995.63
5
1
0.11
1
308.15
5
2
0
6
1
1111.76
6
1
1
1
308.15
5
2
0.10057
5
1
1109.9
6
1
0.9
1
308.15
5
2
0.19483
5
1
1107.93
6
1
0.82
1
308.15
5
2
0.30263
5
1
1105.33
6
1
0.72
1
308.15
5
2
0.40112
5
1
1102.11
6
1
0.65
1
308.15
5
2
0.49793
5
1
1098.18
6
1
0.57
1
308.15
5
2
0.60433
5
1
1092.01
6
1
0.47
1
308.15
5
2
0.68866
5
1
1084.79
6
1
0.39
1
308.15
5
2
0.91048
5
1
1042.25
6
1
0.19
1
308.15
5
2
0.94426
5
1
1028.56
6
1
0.17
1
308.15
5
2
0.95057
5
1
1025.5
6
1
0.16
1
308.15
5
2
1
6
1
994.02
5
1
0.11
1
313.15
5
2
0
6
1
1108.74
6
1
1
1
313.15
5
2
0.10057
5
1
1106.87
6
1
0.9
1
313.15
5
2
0.19483
5
1
1104.91
6
1
0.82
1
313.15
5
2
0.30263
5
1
1102.25
6
1
0.72
1
313.15
5
2
0.40112
5
1
1099.01
6
1
0.64
1
313.15
5
2
0.49793
5
1
1095.05
6
1
0.57
1
313.15
5
2
0.60433
5
1
1088.82
6
1
0.47
1
313.15
5
2
0.68866
5
1
1081.57
6
1
0.39
1
313.15
5
2
0.91048
5
1
1039.26
6
1
0.19
1
313.15
5
2
0.94426
5
1
1025.8
6
1
0.17
1
313.15
5
2
0.95057
5
1
1022.8
6
1
0.15
1
313.15
5
2
1
6
1
992.2
5
1
0.11
1
318.15
5
2
0
6
1
1105.73
6
1
1
1
318.15
5
2
0.10057
5
1
1103.85
6
1
0.9
1
318.15
5
2
0.19483
5
1
1101.87
6
1
0.82
1
318.15
5
2
0.30263
5
1
1099.19
6
1
0.72
1
318.15
5
2
0.40112
5
1
1095.92
6
1
0.64
1
318.15
5
2
0.49793
5
1
1091.92
6
1
0.57
1
318.15
5
2
0.60433
5
1
1085.65
6
1
0.47
1
318.15
5
2
0.68866
5
1
1078.35
6
1
0.39
1
318.15
5
2
0.91048
5
1
1036.21
6
1
0.19
1
318.15
5
2
0.94426
5
1
1022.95
6
1
0.17
1
318.15
5
2
0.95057
5
1
1020
6
1
0.15
1
318.15
5
2
1
6
1
990.2
5
1
0.11
11
3
1
1
1
Principal objective of the work
AB
TRC
8/1/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
288.15
5
2
0
6
1
0.03424
4
1
0.00073
1
288.15
5
2
0.10057
5
1
0.02745
4
1
0.00053
1
288.15
5
2
0.19483
5
1
0.02199
4
1
0.00043
1
288.15
5
2
0.30263
5
1
0.0186
4
1
0.00033
1
288.15
5
2
0.40112
5
1
0.01507
4
1
0.00026
1
288.15
5
2
0.49793
5
1
0.0124
4
1
0.00022
1
288.15
5
2
0.60433
5
1
0.0092
3
1
0.00015
1
288.15
5
2
0.68866
5
1
0.00715
3
1
0.00011
1
288.15
5
2
0.79814
5
1
0.0047
3
1
7e-05
1
288.15
5
2
0.91048
5
1
0.00253
3
1
3e-05
1
288.15
5
2
0.94426
5
1
0.00196
3
1
2e-05
1
288.15
5
2
0.95057
5
1
0.00186
3
1
2e-05
1
288.15
5
2
1
6
1
0.00113
3
1
1e-05
1
293.15
5
2
0
6
1
0.0279
4
1
0.00059
1
293.15
5
2
0.10057
5
1
0.02255
4
1
0.00044
1
293.15
5
2
0.19483
5
1
0.01863
4
1
0.00036
1
293.15
5
2
0.30263
5
1
0.01574
4
1
0.00028
1
293.15
5
2
0.40112
5
1
0.01281
4
1
0.00022
1
293.15
5
2
0.49793
5
1
0.01043
4
1
0.00018
1
293.15
5
2
0.60433
5
1
0.0079
3
1
0.00012
1
293.15
5
2
0.68866
5
1
0.00617
3
1
0.0001
1
293.15
5
2
0.79814
5
1
0.00408
3
1
6e-05
1
293.15
5
2
0.91048
5
1
0.00227
3
1
3e-05
1
293.15
5
2
0.94426
5
1
0.00176
3
1
2e-05
1
293.15
5
2
0.95057
5
1
0.00167
3
1
2e-05
1
293.15
5
2
1
6
1
0.001
3
1
1e-05
1
298.15
5
2
0
6
1
0.02268
4
1
0.00048
1
298.15
5
2
0.10057
5
1
0.01874
4
1
0.00036
1
298.15
5
2
0.19483
5
1
0.01593
4
1
0.00031
1
298.15
5
2
0.30263
5
1
0.01344
4
1
0.00024
1
298.15
5
2
0.40112
5
1
0.01099
4
1
0.00019
1
298.15
5
2
0.49793
5
1
0.00894
3
1
0.00016
1
298.15
5
2
0.60433
5
1
0.00685
3
1
0.00011
1
298.15
5
2
0.68866
5
1
0.00538
3
1
8e-05
1
298.15
5
2
0.91048
5
1
0.00202
3
1
3e-05
1
298.15
5
2
0.94426
5
1
0.00157
3
1
2e-05
1
298.15
5
2
0.95057
5
1
0.00149
3
1
2e-05
1
298.15
5
2
1
6
1
0.00089
2
1
1e-05
1
303.15
5
2
0
6
1
0.01909
4
1
0.00041
1
303.15
5
2
0.10057
5
1
0.01603
4
1
0.00031
1
303.15
5
2
0.19483
5
1
0.01375
4
1
0.00027
1
303.15
5
2
0.30263
5
1
0.01161
4
1
0.0002
1
303.15
5
2
0.40112
5
1
0.00955
3
1
0.00017
1
303.15
5
2
0.49793
5
1
0.00777
3
1
0.00014
1
303.15
5
2
0.60433
5
1
0.00601
3
1
9e-05
1
303.15
5
2
0.68866
5
1
0.00472
3
1
7e-05
1
303.15
5
2
0.91048
5
1
0.00179
3
1
2e-05
1
303.15
5
2
0.94426
5
1
0.00139
3
1
2e-05
1
303.15
5
2
0.95057
5
1
0.00132
3
1
2e-05
1
303.15
5
2
1
6
1
0.0008
2
1
1e-05
1
308.15
5
2
0
6
1
0.01639
4
1
0.00035
1
308.15
5
2
0.10057
5
1
0.01387
4
1
0.00027
1
308.15
5
2
0.19483
5
1
0.01202
4
1
0.00023
1
308.15
5
2
0.30263
5
1
0.01014
4
1
0.00018
1
308.15
5
2
0.40112
5
1
0.00839
3
1
0.00015
1
308.15
5
2
0.49793
5
1
0.00683
3
1
0.00012
1
308.15
5
2
0.60433
5
1
0.00531
3
1
8e-05
1
308.15
5
2
0.68866
5
1
0.00419
3
1
7e-05
1
308.15
5
2
0.91048
5
1
0.0016
3
1
2e-05
1
308.15
5
2
0.94426
5
1
0.00125
3
1
2e-05
1
308.15
5
2
0.95057
5
1
0.00119
3
1
2e-05
1
308.15
5
2
1
6
1
0.00072
2
1
1e-05
1
313.15
5
2
0
6
1
0.01418
4
1
0.0003
1
313.15
5
2
0.10057
5
1
0.01215
4
1
0.00024
1
313.15
5
2
0.19483
5
1
0.01058
4
1
0.00021
1
313.15
5
2
0.30263
5
1
0.00893
3
1
0.00016
1
313.15
5
2
0.40112
5
1
0.00743
3
1
0.00013
1
313.15
5
2
0.49793
5
1
0.00607
3
1
0.00011
1
313.15
5
2
0.60433
5
1
0.00474
3
1
7e-05
1
313.15
5
2
0.68866
5
1
0.00374
3
1
6e-05
1
313.15
5
2
0.91048
5
1
0.00144
3
1
2e-05
1
313.15
5
2
0.94426
5
1
0.00113
3
1
2e-05
1
313.15
5
2
0.95057
5
1
0.00107
3
1
1e-05
1
313.15
5
2
1
6
1
0.00065
2
1
1e-05
1
318.15
5
2
0
6
1
0.01243
4
1
0.00026
1
318.15
5
2
0.10057
5
1
0.01071
4
1
0.00021
1
318.15
5
2
0.19483
5
1
0.00938
3
1
0.00018
1
318.15
5
2
0.30263
5
1
0.00794
3
1
0.00014
1
318.15
5
2
0.40112
5
1
0.00662
3
1
0.00012
1
318.15
5
2
0.49793
5
1
0.00543
3
1
0.0001
1
318.15
5
2
0.60433
5
1
0.00426
3
1
7e-05
1
318.15
5
2
0.68866
5
1
0.00335
3
1
5e-05
1
318.15
5
2
0.91048
5
1
0.00131
3
1
2e-05
1
318.15
5
2
0.94426
5
1
0.00103
3
1
1e-05
1
318.15
5
2
0.95057
5
1
0.00098
2
1
1e-05
1
318.15
5
2
1
6
1
0.0006
2
1
1e-05
12
3
1
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
(Relative) activity
chilled-mirror dew point technique
3
Liquid
Direct value, X
Pure compound
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
290.44
5
2
0.94946
5
1
0.9497
4
1
0.0387
1
293.13
5
2
0.94946
5
1
0.9486
4
1
0.0387
1
298.13
5
2
0.94946
5
1
0.9487
4
1
0.0387
1
303.12
5
2
0.94946
5
1
0.9478
4
1
0.0387
1
308.12
5
2
0.94946
5
1
0.9473
4
1
0.0387
1
313.1
5
2
0.94946
5
1
0.9469
4
1
0.0387
1
318.13
5
2
0.94946
5
1
0.9456
4
1
0.0387
1
293.12
5
2
0.89829
5
1
0.8902
4
1
0.0387
1
298.14
5
2
0.89829
5
1
0.8894
4
1
0.0387
1
303.13
5
2
0.89829
5
1
0.8893
4
1
0.0387
1
308.12
5
2
0.89829
5
1
0.888
4
1
0.0387
1
313.11
5
2
0.89829
5
1
0.8862
4
1
0.0387
1
318.13
5
2
0.89829
5
1
0.8846
4
1
0.0387
1
290.12
5
2
0.80037
5
1
0.7207
4
1
0.0387
1
293.14
5
2
0.80037
5
1
0.7209
4
1
0.0387
1
298.14
5
2
0.80037
5
1
0.7215
4
1
0.0387
1
303.12
5
2
0.80037
5
1
0.7214
4
1
0.0387
1
308.12
5
2
0.80037
5
1
0.7212
4
1
0.0387
1
313.11
5
2
0.80037
5
1
0.7204
4
1
0.0387
1
318.13
5
2
0.80037
5
1
0.7195
4
1
0.0387
1
290.11
5
2
0.70234
5
1
0.5382
4
1
0.0387
1
293.12
5
2
0.70234
5
1
0.5382
4
1
0.0387
1
298.12
5
2
0.70234
5
1
0.5391
4
1
0.0387
1
303.11
5
2
0.70234
5
1
0.54
4
1
0.0387
1
308.11
5
2
0.70234
5
1
0.5403
4
1
0.0387
1
313.1
5
2
0.70234
5
1
0.5405
4
1
0.0387
1
318.12
5
2
0.70234
5
1
0.5404
4
1
0.0387
1
290.09
5
2
0.60269
5
1
0.3798
4
1
0.0387
1
293.1
5
2
0.60269
5
1
0.3798
4
1
0.0387
1
298.1
5
2
0.60269
5
1
0.3811
4
1
0.0387
1
303.09
5
2
0.60269
5
1
0.3822
4
1
0.0387
1
308.09
5
2
0.60269
5
1
0.3828
4
1
0.0387
1
313.08
5
2
0.60269
5
1
0.3834
4
1
0.0387
1
318.1
5
2
0.60269
5
1
0.3838
4
1
0.0387
1
293.07
5
2
0.50171
5
1
0.2639
4
1
0.0387
1
298.09
5
2
0.50171
5
1
0.2649
4
1
0.0387
1
303.07
5
2
0.50171
5
1
0.2654
4
1
0.0387
1
308.07
5
2
0.50171
5
1
0.266
4
1
0.0387
1
313.05
5
2
0.50171
5
1
0.2667
4
1
0.0387
1
318.08
5
2
0.50171
5
1
0.2671
4
1
0.0387
1
290.06
5
2
0.40125
5
1
0.1776
4
1
0.0387
1
293.07
5
2
0.40125
5
1
0.1777
4
1
0.0387
1
298.08
5
2
0.40125
5
1
0.1785
4
1
0.0387
1
303.05
5
2
0.40125
5
1
0.1791
4
1
0.0387
1
308.05
5
2
0.40125
5
1
0.1795
4
1
0.0387
1
313.04
5
2
0.40125
5
1
0.1799
4
1
0.0387
1
318.05
5
2
0.40125
5
1
0.1803
4
1
0.0387
1
290.09
5
2
0.30376
5
1
0.1177
4
1
0.0387
1
293.05
5
2
0.30376
5
1
0.1182
4
1
0.0387
1
298.06
5
2
0.30376
5
1
0.1182
4
1
0.0387
1
303.03
5
2
0.30376
5
1
0.1184
4
1
0.0387
1
308.03
5
2
0.30376
5
1
0.1187
4
1
0.0387
1
313.02
5
2
0.30376
5
1
0.1189
4
1
0.0387
1
318.03
5
2
0.30376
5
1
0.1192
4
1
0.0387
1
290.09
5
2
0.20544
5
1
0.0722
3
1
0.0387
1
293.03
5
2
0.20544
5
1
0.072
3
1
0.0387
1
298.03
5
2
0.20544
5
1
0.072
3
1
0.0387
1
303.01
5
2
0.20544
5
1
0.0722
3
1
0.0387
1
308.01
5
2
0.20544
5
1
0.0723
3
1
0.0387
1
312.99
5
2
0.20544
5
1
0.0726
3
1
0.0387
1
318.01
5
2
0.20544
5
1
0.0728
3
1
0.0387
13
3
1
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
288.15
5
2
0.003363
4
1
0.00923
3
1
0.00086
1
288.15
5
2
0.002804
4
1
0.00776
3
1
0.00084
1
288.15
5
2
0.002244
4
1
0.00625
3
1
0.00083
1
288.15
5
2
0.001684
4
1
0.00469
3
1
0.00081
1
288.15
5
2
0.001123
4
1
0.00311
3
1
0.0008
1
288.15
5
2
0.000562
3
1
0.00151
3
1
0.00079
1
298.15
5
2
0.003363
4
1
0.01073
4
1
0.0009
1
298.15
5
2
0.002804
4
1
0.00901
3
1
0.00086
1
298.15
5
2
0.002244
4
1
0.00727
3
1
0.00083
1
298.15
5
2
0.001684
4
1
0.00547
3
1
0.00082
1
298.15
5
2
0.001123
4
1
0.00363
3
1
0.0008
1
298.15
5
2
0.000562
3
1
0.00175
3
1
0.00079
1
308.15
5
2
0.003362
4
1
0.01275
4
1
0.00096
1
308.15
5
2
0.002803
4
1
0.0107
4
1
0.0009
1
308.15
5
2
0.002243
4
1
0.00864
3
1
0.00085
1
308.15
5
2
0.001683
4
1
0.00652
3
1
0.00083
1
308.15
5
2
0.001123
4
1
0.00435
3
1
0.00081
1
308.15
5
2
0.000562
3
1
0.00214
3
1
0.00079
1
318.15
5
2
0.003359
4
1
0.01492
4
1
0.00102
1
318.15
5
2
0.0028
4
1
0.01253
4
1
0.00095
1
318.15
5
2
0.002241
4
1
0.0101
4
1
0.00088
1
318.15
5
2
0.001682
4
1
0.00762
3
1
0.00084
1
318.15
5
2
0.001122
4
1
0.00508
3
1
0.00082
1
318.15
5
2
0.000561
3
1
0.00246
3
1
0.00079
14
3
1
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
288.15
5
2
0.003363
4
1
1002.694
7
1
0.112
1
288.15
5
2
0.002804
4
1
1002.132
7
1
0.11
1
288.15
5
2
0.002244
4
1
1001.555
7
1
0.109
1
288.15
5
2
0.001684
4
1
1000.96
7
1
0.108
1
288.15
5
2
0.001123
4
1
1000.357
7
1
0.107
1
288.15
5
2
0.000562
3
1
999.731
6
1
0.106
1
298.15
5
2
0.003363
4
1
1000.245
7
1
0.107
1
298.15
5
2
0.002804
4
1
999.738
6
1
0.109
1
298.15
5
2
0.002244
4
1
999.224
6
1
0.108
1
298.15
5
2
0.001684
4
1
998.701
6
1
0.108
1
298.15
5
2
0.001123
4
1
998.161
6
1
0.107
1
298.15
5
2
0.000562
3
1
997.606
6
1
0.107
1
308.15
5
2
0.003362
4
1
996.914
6
1
0.107
1
308.15
5
2
0.002803
4
1
996.456
6
1
0.109
1
308.15
5
2
0.002243
4
1
995.993
6
1
0.108
1
308.15
5
2
0.001683
4
1
995.519
6
1
0.108
1
308.15
5
2
0.001123
4
1
995.038
6
1
0.107
1
308.15
5
2
0.000562
3
1
994.54
6
1
0.107
1
318.15
5
2
0.003359
4
1
992.819
6
1
0.11
1
318.15
5
2
0.0028
4
1
992.407
6
1
0.109
1
318.15
5
2
0.002241
4
1
991.986
6
1
0.109
1
318.15
5
2
0.001682
4
1
991.559
6
1
0.108
1
318.15
5
2
0.001122
4
1
991.121
6
1
0.108
1
318.15
5
2
0.000561
3
1
990.667
6
1
0.108
15
3
1
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
288.15
5
2
0
6
1
1108.12
6
1
2.02
1
288.15
5
2
0.10164
5
1
1106.34
6
1
1.82
1
288.15
5
2
0.20135
5
1
1104.34
6
1
1.63
1
288.15
5
2
0.29995
5
1
1101.9
6
1
1.45
1
288.15
5
2
0.40147
5
1
1098.75
6
1
1.25
1
288.15
5
2
0.51064
5
1
1094.6
6
1
1.03
1
288.15
5
2
0.5934
5
1
1090.52
6
1
0.89
1
288.15
5
2
0.74651
5
1
1078.84
6
1
0.59
1
288.15
5
2
0.79741
5
1
1072.73
6
1
0.49
1
288.15
5
2
0.90037
5
1
1052.16
6
1
0.29
1
288.15
5
2
0.94978
5
1
1033.9
6
1
0.21
1
288.15
5
2
1
6
1
999.09
5
1
0.11
1
293.15
5
2
0
6
1
1104.77
6
1
2.02
1
293.15
5
2
0.10164
5
1
1102.98
6
1
1.82
1
293.15
5
2
0.20135
5
1
1100.97
6
1
1.63
1
293.15
5
2
0.29995
5
1
1098.51
6
1
1.45
1
293.15
5
2
0.40147
5
1
1095.35
6
1
1.25
1
293.15
5
2
0.51064
5
1
1091.17
6
1
1.03
1
293.15
5
2
0.5934
5
1
1087.07
6
1
0.89
1
293.15
5
2
0.74651
5
1
1075.38
6
1
0.59
1
293.15
5
2
0.79741
5
1
1069.3
6
1
0.49
1
293.15
5
2
0.90037
5
1
1049.05
6
1
0.29
1
293.15
5
2
0.94978
5
1
1031.35
6
1
0.21
1
293.15
5
2
1
6
1
998.2
5
1
0.11
1
298.15
5
2
0
6
1
1101.44
6
1
2.02
1
298.15
5
2
0.10164
5
1
1099.64
6
1
1.82
1
298.15
5
2
0.20135
5
1
1097.62
6
1
1.63
1
298.15
5
2
0.29995
5
1
1095.14
6
1
1.45
1
298.15
5
2
0.40147
5
1
1091.95
6
1
1.25
1
298.15
5
2
0.51064
5
1
1087.75
6
1
1.03
1
298.15
5
2
0.5934
5
1
1083.63
6
1
0.89
1
298.15
5
2
0.74651
5
1
1071.91
6
1
0.59
1
298.15
5
2
0.79741
5
1
1065.85
6
1
0.49
1
298.15
5
2
0.90037
5
1
1045.89
6
1
0.29
1
298.15
5
2
0.94978
5
1
1028.7
6
1
0.21
1
298.15
5
2
1
6
1
997.04
5
1
0.11
1
303.15
5
2
0
6
1
1098.12
6
1
2.02
1
303.15
5
2
0.10164
5
1
1096.31
6
1
1.82
1
303.15
5
2
0.20135
5
1
1094.28
6
1
1.63
1
303.15
5
2
0.29995
5
1
1091.78
6
1
1.45
1
303.15
5
2
0.40147
5
1
1088.58
6
1
1.25
1
303.15
5
2
0.51064
5
1
1084.34
6
1
1.03
1
303.15
5
2
0.5934
5
1
1080.19
6
1
0.89
1
303.15
5
2
0.74651
5
1
1068.44
6
1
0.59
1
303.15
5
2
0.79741
5
1
1062.4
6
1
0.49
1
303.15
5
2
0.90037
5
1
1042.69
6
1
0.29
1
303.15
5
2
0.94978
5
1
1025.95
6
1
0.21
1
303.15
5
2
1
6
1
995.65
5
1
0.11
1
308.15
5
2
0
6
1
1094.83
6
1
2.02
1
308.15
5
2
0.10164
5
1
1093
6
1
1.82
1
308.15
5
2
0.20135
5
1
1090.95
6
1
1.63
1
308.15
5
2
0.29995
5
1
1088.44
6
1
1.45
1
308.15
5
2
0.40147
5
1
1085.21
6
1
1.25
1
308.15
5
2
0.51064
5
1
1080.95
6
1
1.03
1
308.15
5
2
0.5934
5
1
1076.77
6
1
0.89
1
308.15
5
2
0.74651
5
1
1064.98
6
1
0.59
1
308.15
5
2
0.79741
5
1
1058.94
6
1
0.49
1
308.15
5
2
0.90037
5
1
1039.45
6
1
0.29
1
308.15
5
2
0.94978
5
1
1023.11
6
1
0.21
1
308.15
5
2
1
6
1
994.03
5
1
0.11
1
313.15
5
2
0
6
1
1091.54
6
1
2.02
1
313.15
5
2
0.10164
5
1
1089.71
6
1
1.82
1
313.15
5
2
0.20135
5
1
1087.65
6
1
1.63
1
313.15
5
2
0.29995
5
1
1085.12
6
1
1.45
1
313.15
5
2
0.40147
5
1
1081.86
6
1
1.25
1
313.15
5
2
0.51064
5
1
1077.57
6
1
1.03
1
313.15
5
2
0.5934
5
1
1073.36
6
1
0.89
1
313.15
5
2
0.74651
5
1
1061.51
6
1
0.59
1
313.15
5
2
0.79741
5
1
1055.48
6
1
0.49
1
313.15
5
2
0.90037
5
1
1036.16
6
1
0.29
1
313.15
5
2
0.94978
5
1
1020.19
6
1
0.21
1
313.15
5
2
1
6
1
992.22
5
1
0.11
1
318.15
5
2
0
6
1
1088.28
6
1
2.02
1
318.15
5
2
0.10164
5
1
1086.44
6
1
1.82
1
318.15
5
2
0.20135
5
1
1084.36
6
1
1.63
1
318.15
5
2
0.29995
5
1
1081.81
6
1
1.45
1
318.15
5
2
0.40147
5
1
1078.53
6
1
1.25
1
318.15
5
2
0.51064
5
1
1074.2
6
1
1.03
1
318.15
5
2
0.5934
5
1
1069.96
6
1
0.89
1
318.15
5
2
0.74651
5
1
1058.04
6
1
0.59
1
318.15
5
2
0.79741
5
1
1052.01
6
1
0.49
1
318.15
5
2
0.90037
5
1
1032.84
6
1
0.29
1
318.15
5
2
0.94978
5
1
1017.18
6
1
0.21
1
318.15
5
2
1
6
1
990.21
5
1
0.11
16
3
1
2
1
Principal objective of the work
AB
TRC
8/1/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
288.15
5
2
0
6
1
0.01998
4
1
0.00121
1
288.15
5
2
0.10164
5
1
0.01749
4
1
0.00096
1
288.15
5
2
0.20135
5
1
0.01514
4
1
0.00077
1
288.15
5
2
0.29995
5
1
0.01302
4
1
0.00061
1
288.15
5
2
0.40147
5
1
0.01108
4
1
0.00045
1
288.15
5
2
0.51064
5
1
0.00924
3
1
0.00032
1
288.15
5
2
0.5934
5
1
0.00786
3
1
0.00024
1
288.15
5
2
0.74651
5
1
0.00545
3
1
0.00013
1
288.15
5
2
0.79741
5
1
0.00458
3
1
0.0001
1
288.15
5
2
0.90037
5
1
0.00276
3
1
4e-05
1
288.15
5
2
0.94978
5
1
0.00193
3
1
3e-05
1
288.15
5
2
1
6
1
0.00113
3
1
1e-05
1
293.15
5
2
0
6
1
0.01693
4
1
0.00103
1
293.15
5
2
0.10164
5
1
0.01489
4
1
0.00081
1
293.15
5
2
0.20135
5
1
0.01298
4
1
0.00066
1
293.15
5
2
0.29995
5
1
0.01123
4
1
0.00052
1
293.15
5
2
0.40147
5
1
0.00959
3
1
0.00039
1
293.15
5
2
0.51064
5
1
0.008
3
1
0.00028
1
293.15
5
2
0.5934
5
1
0.00683
3
1
0.00021
1
293.15
5
2
0.74651
5
1
0.00474
3
1
0.00011
1
293.15
5
2
0.79741
5
1
0.00399
3
1
9e-05
1
293.15
5
2
0.90037
5
1
0.00241
3
1
4e-05
1
293.15
5
2
0.94978
5
1
0.00169
3
1
2e-05
1
293.15
5
2
1
6
1
0.001
3
1
1e-05
1
298.15
5
2
0
6
1
0.01454
4
1
0.00088
1
298.15
5
2
0.10164
5
1
0.01286
4
1
0.0007
1
298.15
5
2
0.20135
5
1
0.01123
4
1
0.00057
1
298.15
5
2
0.29995
5
1
0.00977
3
1
0.00046
1
298.15
5
2
0.40147
5
1
0.00837
3
1
0.00034
1
298.15
5
2
0.51064
5
1
0.00701
3
1
0.00024
1
298.15
5
2
0.5934
5
1
0.00599
3
1
0.00019
1
298.15
5
2
0.74651
5
1
0.00416
3
1
0.0001
1
298.15
5
2
0.79741
5
1
0.0035
3
1
7e-05
1
298.15
5
2
0.90037
5
1
0.00213
3
1
3e-05
1
298.15
5
2
0.94978
5
1
0.0015
3
1
2e-05
1
298.15
5
2
1
6
1
0.00089
2
1
1e-05
1
303.15
5
2
0
6
1
0.01263
4
1
0.00077
1
303.15
5
2
0.10164
5
1
0.01121
4
1
0.00061
1
303.15
5
2
0.20135
5
1
0.00984
3
1
0.0005
1
303.15
5
2
0.29995
5
1
0.00859
3
1
0.0004
1
303.15
5
2
0.40147
5
1
0.00738
3
1
0.0003
1
303.15
5
2
0.51064
5
1
0.00619
3
1
0.00022
1
303.15
5
2
0.5934
5
1
0.00529
3
1
0.00016
1
303.15
5
2
0.74651
5
1
0.00367
3
1
9e-05
1
303.15
5
2
0.79741
5
1
0.00309
3
1
7e-05
1
303.15
5
2
0.90037
5
1
0.00189
3
1
3e-05
1
303.15
5
2
0.94978
5
1
0.00134
3
1
2e-05
1
303.15
5
2
1
6
1
0.00079
2
1
1e-05
1
308.15
5
2
0
6
1
0.01105
4
1
0.00067
1
308.15
5
2
0.10164
5
1
0.00986
3
1
0.00054
1
308.15
5
2
0.20135
5
1
0.00869
3
1
0.00044
1
308.15
5
2
0.29995
5
1
0.00761
3
1
0.00036
1
308.15
5
2
0.40147
5
1
0.00655
3
1
0.00027
1
308.15
5
2
0.51064
5
1
0.0055
3
1
0.00019
1
308.15
5
2
0.5934
5
1
0.00471
3
1
0.00015
1
308.15
5
2
0.74651
5
1
0.00327
3
1
8e-05
1
308.15
5
2
0.79741
5
1
0.00276
3
1
6e-05
1
308.15
5
2
0.90037
5
1
0.0017
3
1
3e-05
1
308.15
5
2
0.94978
5
1
0.0012
3
1
2e-05
1
308.15
5
2
1
6
1
0.00072
2
1
1e-05
1
313.15
5
2
0
6
1
0.00976
3
1
0.00059
1
313.15
5
2
0.10164
5
1
0.00874
3
1
0.00048
1
313.15
5
2
0.20135
5
1
0.00773
3
1
0.00039
1
313.15
5
2
0.29995
5
1
0.00679
3
1
0.00032
1
313.15
5
2
0.40147
5
1
0.00586
3
1
0.00024
1
313.15
5
2
0.51064
5
1
0.00493
3
1
0.00017
1
313.15
5
2
0.5934
5
1
0.00423
3
1
0.00013
1
313.15
5
2
0.74651
5
1
0.00293
3
1
7e-05
1
313.15
5
2
0.79741
5
1
0.00248
3
1
5e-05
1
313.15
5
2
0.90037
5
1
0.00153
3
1
2e-05
1
313.15
5
2
0.94978
5
1
0.00109
3
1
2e-05
1
313.15
5
2
1
6
1
0.00065
2
1
1e-05
1
318.15
5
2
0
6
1
0.00869
3
1
0.00053
1
318.15
5
2
0.10164
5
1
0.00779
3
1
0.00043
1
318.15
5
2
0.20135
5
1
0.00692
3
1
0.00035
1
318.15
5
2
0.29995
5
1
0.0061
3
1
0.00028
1
318.15
5
2
0.40147
5
1
0.00527
3
1
0.00021
1
318.15
5
2
0.51064
5
1
0.00445
3
1
0.00016
1
318.15
5
2
0.5934
5
1
0.00381
3
1
0.00012
1
318.15
5
2
0.74651
5
1
0.00264
3
1
6e-05
1
318.15
5
2
0.79741
5
1
0.00224
3
1
5e-05
1
318.15
5
2
0.90037
5
1
0.00139
3
1
2e-05
1
318.15
5
2
0.94978
5
1
0.00099
2
1
1e-05
1
318.15
5
2
1
6
1
0.00059
2
1
1e-05