Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental investigation of hydrogen sulfide solubility in aqueous sulfolane solution

Shokouhi, M.[Mohammad], Jalili, A. H.[Amir Hossein], Zoghi, A. T.[Ali Taghi]
J. Chem. Thermodyn. 2017, 106, 232-242
ABSTRACT
New experimental data are presented for the solubility of hydrogen sulfide in aqueous sulfolane solution which is an important topic in many areas of chemical engineering. Solvent mixtures of (SFL + H2O) contain the composition range from xSFL = 0.0113 to xSFL = 0.939, temperatures from (303.15 to 353.15) K with step 10 K and total pressures up to 2.0 MPa. Henry s constant of H2S in pure SFL, pure H2O and mixed (SFL + H2O) are reported on the mole fraction and molality base. Model for the Gibbs excess energy of mixed solvent is used to correlate the obtained experimental data.
Compounds
# Formula Name
1 H2S hydrogen sulfide
2 C4H8O2S sulfolane
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • volumetric method
  • 328