Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experiments and model for the surface tension of DEAE-PZ and DEAE-MEA aqueous solutions

Fu, D.[Dong], Wang, L.[LeMeng], Tian, X.[XiangFeng]
J. Chem. Thermodyn. 2017, 105, 71-75
ABSTRACT
The surface tension (c) of 2-diethylaminoethanol (DEAE), DEAE-monoethanolamine (MEA), and DEAEpiperazine (PZ) aqueous solutions was measured by using the BZY-1 surface tension meter. The temperature ranged from 303.2 K to 323.2 K. The mass fraction of DEAE, MEA and PZ respectively ranged from 0.30 to 0.50, 0.05 to 0.15 and 0.025 to 0.075. An equation was proposed to model the surface tension and the calculated results agreed well with the experiments. The effects of temperature and mass fraction of amines on the surface tension were demonstrated on the basis of experiments and calculations.
Compounds
# Formula Name
1 C6H15NO (diethylamino)ethanol
2 C2H7NO 2-aminoethan-1-ol
3 C4H10N2 piperazine
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 5
  • POMD
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 1
  • POMD
  • 1
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 37
  • POMD
  • 1
  • 2
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 27
  • POMD
  • 1
  • 3
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 3; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhemy plate method
  • 27