Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Absorption capacity and viscosity for CO2 capture process using high concentrated PZ-DEAE aqueous solution

Fu, D.[Dong], Wang, L.[LeMeng], Mi, C.[ChenLu], Zhang, P.[Pan]
J. Chem. Thermodyn. 2016, 101, 123-129
ABSTRACT
The absorption capacity of CO2 in piperazine (PZ) promoted 2-diethylaminoethanol (DEAE) aqueous solution was measured. The viscosities of both CO2-unloaded and CO2-loaded PZ-DEAE aqueous solutions were measured and then modelled. The temperatures ranged from 303.2 K to 323.2 K. The mass fraction of PZ and DEAE respectively ranged from 0 to 0.075 and 0.3 to 0.5. The temperature and concentration dependences of absorption capacity were determined. The effects of temperature, mass fraction and CO2 loading on viscosities are demonstrated.
Compounds
# Formula Name
1 H2O water
2 CO2 carbon dioxide
3 C6H15NO (diethylamino)ethanol
4 C4H10N2 piperazine
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 2
  • 1
  • Mass ratio of solute to solvent - 2 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • volumetric
  • 9
  • POMD
  • 3
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 12
  • POMD
  • 3
  • 4
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 3; Liquid
  • Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 27