Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Equilibrium solubility of sodium 2,4-diaminobenzene sulfonate in liquid mixtures (methanol + water, isopropanol + water, and 1,2-propanediol + water) from 273.15 K to 323.15 K

Li, R.[Rongrong], Weng, J.[Jiaqi], Ye, C.[Cuihong], Ying, A.[Anguo], Zhou, Q.[Qizhong], Zhong, A.[Aiguo], Chen, H.[Hao], Yang, J.[Jianguo]
J. Chem. Thermodyn. 2016, 100, 1-6
ABSTRACT
The equilibrium solubility of sodium 2,4-diaminobenzene sulfonate in liquid mixtures (methanol + water, isopropanol + water, and 1,2-propanediol + water) were determined at temperatures ranging from (273.15 to 323.15) K. The solubility of sodium 2,4-diaminobenzene sulfonate increased with temperature increment but decreased with the concentrations of methanol, isopropanol or 1,2-propanediol in liquid mixtures. The obtained solubility data were correlated by Apelblat equation and Sun model. On the base of the measured solubility, the dissolution enthalpy (DHo sol) of the dissolution process were calculated.
Compounds
# Formula Name
1 C6H7N2NaO3S sodium 2,4-diaminobenzenesulfonate
2 CH4O methanol
3 C3H8O propan-2-ol
4 C3H8O2 1,2-propanediol
5 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • 5
  • Mole fraction - 1 ; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 55
  • POMD
  • 3
  • 1
  • 5
  • Mole fraction - 1 ; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 55
  • POMD
  • 4
  • 1
  • 5
  • Mole fraction - 1 ; Liquid
  • Solvent: Mass fraction - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 55
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 11
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 11
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 11