Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Measurement and correlation of solubility of pronamide in five organic solvents at (278.15-323.15) K

Guo, H.[Huai], Song, L.[Liangcheng], Zhu, C.[Chongqiang], Wu, D.[Di], Yang, C.[Chunhui]
J. Chem. Thermodyn. 2016, 99, 11-15
ABSTRACT
The solubility of pronamide in five organic solvents (ethanol, methanol, isopropanol, toluene and cyclohexane) at the temperature range from (278.15 to 323.15) K was measured by a dynamic equilibrium method. The results showed that the solubility of pronamide increased with the increasing temperature in all the solvents involved. The experimental values were correlated by the Apelblat equation, and a good fitting result was confirmed by the low level of root-mean-square deviations (less than4.0*10^-4). Moreover, the apparent dissolving enthalpies and entropies, were derived from simplified van t Hoff equation. The positive values of enthalpies and entropies revealed that the dissolution of pronamide in the selected solvents was an endothermic and entropy-driven process.
Compounds
# Formula Name
1 C12H11Cl2NO 3,5-dichloro-N-(1,1-dimethylpropynyl)benzamide
2 C2H6O ethanol
3 CH4O methanol
4 C3H8O propan-2-ol
5 C6H12 cyclohexane
6 C7H8 toluene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Crystal
  • Temperature, K; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • X-ray diffraction
  • 1
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 10
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 10
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 10
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 10
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 9