Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Densities of unloaded and CO2-loaded 3-dimethylamino-1-propanol at temperatures (293.15 to 343.15) K

Idris, Z.[Zulkifli], Chen, J.[Jia], Eimer, D. A.[Dag A.]
J. Chem. Thermodyn. 2016, 97, 282-289
ABSTRACT
This article reports experimental density values of aqueous 3-dimethylamino-1-propanol (3DMA1P) solutions over the entire range of 3DMA1P mass fractions and temperatures of (293.15 to 343.15) K. Based on the experimental results, corresponding values of thermal expansion and excess molar volume of 3DMA1P solutions were established. A second order Redlich Kister polynomial equation satisfactorily correlates excess molar volumes against mole fractions of 3DMA1P solutions, and regression of these parameters as a function of temperature is demonstrated. Densities of carbonated 3DMA1P solutions were also measured at three 3DMA1P mass fractions of 0.20, 0.30 and 0.50, at different CO2-loadings up to 0.8 mol CO2/mol 3DMA1P, and temperatures. These data were modeled. A comparison between experimental and calculated values are discussed.
Compounds
# Formula Name
1 C5H13NO 3-dimethylamino-1-propanol
2 CO2 carbon dioxide
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 11
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 11
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 121
  • POMD
  • 2
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mass fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 187