Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Interfacial tension between (CO2 + N2) gas and tetrabutylammonium bromide aqueous solution

Akiba, H.[Hotaka], Ohmura, R.[Ryo]
J. Chem. Thermodyn. 2016, 97, 83-87
ABSTRACT
This paper reports experimental values of the interfacial tension between (CO2 + N2) gas and tetrabutylammonium bromide aqueous solution (TBABaq). The experiments were performed by the pendant drop method in conditions from P = (1.00 to 4.00) MPa, from T = (288.15 to 303.15) K and from wTBAB = (0.10 to 0.40), where wTBAB denotes the mass fraction of TBAB in the aqueous solution. The interfacial tension decreased with increasing wTBAB and pressure. The depletion of the interfacial tension with increasing wTBAB in the (CO2 + N2 + TBABaq) system was consistent with that in (CO2 + TBABaq) system. The depletion ratio of the pressure gradient of the interfacial tension caused by the addition of TBAB in (CO2 + N2 + water) system was almost the same as that in (CO2 + water) system. There might be little effect on the interfacial tension caused by the interaction between gases and tetrabutylammonium ions. The temperature dependence of c was not observed as well as in the (CO2 + TBABaq) system.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 N2 nitrogen
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Volume fraction - 1; Gas
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Pendant drop shape
  • 4