ABSTRACT

Density (q), refractive index (nD) and speed of sound (u) values are measured for the binary mixture of 1-butyl-3-methylimidazolium tetrafluoroborate and 2-pyrrolidone over the entire range of mole fraction at temperatures from (298.15 to 323.15) K under atmospheric pressure. Using the basic experimental data, molar volume (Vm), isentropic compressibility (ks), intermolecular free length (Lf ), molar refraction (Rm), excess molar volume (VE m), excess isentropic compressibility (jEs ) and excess intermolecular free length (LEf ) values are calculated. The calculated properties are discussed in terms of molecular interactions between the present investigated system. The excess values are fitted to Redlich Kister polynomial equation to estimate the binary coefficients and standard deviation between the experimental and calculated values. Further, the molecular interactions in the binary mixture system are analysed using the experimental FT-IR spectrum recorded at room temperature.

Compounds

#	Formula	Name
1	C8H15BF4N2	1-butyl-3-methylimidazolium tetrafluoroborate
2	C4H7NO	2-pyrrolidinone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	6
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	6
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	6
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	66
POMD	2 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	66
POMD	2 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	66

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric properties of 1-butyl-3-methylimidazolium tetrafluoroborate and 2-pyrrolidone from T = (298.15 to 323.15) K at atmospheric pressure

Govardhana Rao, S., Madhu Mohan, T., Vijaya Krishna, T., Subba Rao, B.

ABSTRACT