Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Surface tension between CO2 gas and tetra-n-butylammonium bromide aqueous solution

Akiba, H.[Hotaka], Ohmura, R.[Ryo]
J. Chem. Thermodyn. 2016, 92, 72-75
ABSTRACT
This paper reports experimental values of the surface tension between CO2 gas and tetra-nbutylammonium bromide (TBAB) aqueous solution measured by the pendant drop method. The experimental conditions were pressures from 1.00 MPa to 4.00 MPa, temperatures from 288.15 K to 303.15 K and wTBAB from 0.10 to 0.40, where wTBAB denotes the mass fraction of TBAB in the aqueous solution. These pressure temperature-composition conditions partially fall into the stability zone of (CO2 + TBAB) semiclathrate hydrate but all data were obtained without any hydrate in the system. Surface tension decreased with increasing wTBAB and pressure but temperature dependency was not observed. Compared to the air TBAB aqueous solution system and CO2 water system, the values of the surface tension were smaller.
Compounds
# Formula Name
1 C16H36BrN tetrabutylammonium bromide
2 H2O water
3 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Pendant drop shape
  • 5
  • POMD
  • 3
  • 1
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Gas
  • Pendant drop shape
  • 40