Previous work on the binary phase diagram (CsNO3 + TlNO3) showed, in particular, the existence of a continuous solid solution, CsxTl1 xNO3. It extends over the whole composition range between T = 430 K and T = 480 K. Mixing enthalpies of the solid solutions CsxTl1 xNO3 are measured at T = (473 +- 1) K, for the first time, by using a drop calorimetric method. They exhibit a positive and asymmetrical deviation from ideality.
Compounds
#
Formula
Name
1
CsNO3
cesium nitrate
2
NO3Tl
thallium nitrate
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
1
2
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Crystal