Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

Schultz, S. M.[Shannon M.], Harris, H. H.[Harold H.], Chickos, J. S.[James S.]
J. Chem. Thermodyn. 2015, 89, 306-311
ABSTRACT
The vapor pressure and vaporization enthalpy of codlemone (trans, trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 +- 2.6) kJ mol 1 and a vapor pressure, p/Pa = (0.083 +- 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of TB = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of TB= (549.1 +- 0.1) K is also estimated by extrapolation.
Compounds
# Formula Name
1 C12H22O (E,E)-8,10-dodecadien-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1