Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

Two novel ionic liquids based on serine [Cnmim][Ser] (n = 3,4) were prepared by the neutralization method and their structures were confirmed by 1H NMR spectroscopy and differential scanning calorimetry (DSC). The density, surface tension, and refractive index of the two ILs were measured from T = (298.15 to 338.15) K. Since these ILs [Cnmim][Ser] (n = 3,4) could form strong hydrogen bonds with water, small amount of water in the ILs is difficult to removed by common methods. In order to eliminate the effect of trace of water, the standard addition method (SAM) was applied to these measurements. On the basis of the experimental data, the speed of sound (l), thermal expansion coefficient (a), molecular volume (Vm), standard entropy (S0298), entropy of surface (Sa), energy of surface (Ea), parachor (P), molar polarization (Rm), and polarization coefficient (ap) were calculated, and the relationship between each of these properties of [Cnmim][Ser] (n = 3,4) and temperatures was discussed. According to the additivity, the average value of anionic parachor, P (ave), was 180.81 for [Ser] . At the same time, the surface tension of these serine ionic liquids could be estimated from their parachor and refractive index. The estimated values of the surface tension and the corresponding experimental data were almost identical.