Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Thermophysical property characterization of aqueous amino acid salt solutions containing .alpha.-aminobutyric acid

Garcia, A. A.[Alexis A.], Leron, R. B.[Rhoda B.], Soriano, A. N.[Allan N.], Li, M. -H.[Meng-Hui]
J. Chem. Thermodyn. 2015, 81, 136-142
ABSTRACT
In this study, density, electrical conductivity, refractive index and viscosity of aqueous potassium and sodium salt solutions of a-aminobutyric acid were presented. Measurements were done over the temperature range (303.15 to 343.15) K and atmospheric pressure for salt compositions from x1 = 0.009 to 0.062. A modified Graber et al. equation was used to correlate the density, electrical conductivity, and refractive index with temperature and composition leading to average absolute deviations (AAD) between the predicted and calculated values of 0.04%, 0.7%, and 0.01%, respectively. The viscosity data were represented as a function of temperature and composition via Vogel Tamman Fulcher (VTF) type equation at an AAD of 0.6%.
Compounds
# Formula Name
1 C4H8NNaO2 sodium DL-.alpha.-aminobutyrate
2 C4H8KNO2 potassium 2-aminobutanoate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 9
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 9
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 63
  • POMD
  • 3
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 63
  • POMD
  • 3
  • 2
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 54
  • POMD
  • 3
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 63
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 63
  • POMD
  • 3
  • 1
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 63
  • POMD
  • 3
  • 1
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 54
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 63