Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Gaseous pVTx measurements for (HFC134a + HC290) by a compact single-sinker densimeter

Zhang, H.[Haiyang], Gong, M.[Maoqiong], Li, H.[Huiya], Guo, H.[Hao], Dong, X.[Xueqiang], Wu, J.[Jianfeng]
J. Chem. Thermodyn. 2015, 81, 60-65
ABSTRACT
Comprehensive gaseous pVTx measurements for {1,1,1,2-tetrafluoroethane (HFC134a) + propane (HC290)} were carried out by a compact single-sinker densimeter, based on the Archimedes buoyancy principle, at temperatures from (258 to 294) K, pressures up to 0.86 MPa, and mole fractions of HFC134a from (0.2391 to 0.7989). The overall experimental standard uncertainty in temperature, pressure, mole fraction and density were estimated to be less than 5 mK, 176 Pa, (0.02 and 0.05)%, respectively. A truncated virial equation of state was employed to correlate the experimental pVTx data of (HFC134a + HC290) mixtures. This equation represented the experimental pressures and densities with average absolute relative deviations of (0.043 and 0.046)%, respectively.
Compounds
# Formula Name
1 C2H2F4 1,1,1,2-tetrafluoroethane
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • Buoyancy - hydrostatic balance with magnetic suspension - one sinker
  • 147