ABSTRACT

The fundamental physical properties including density, viscosity, refractive index and relative permittivity, have been measured for binary mixtures of exo-tetrahydrodicyclopentadiene (JP-10) with four octane isomers (n-octane, 3-methylheptane, 2,4-dimethylhexane and 2,2,4-trimethylpentane) over the whole composition range at temperatures T = (293.15 to 313.15) K and pressure p = 0.1 MPa. The values of excess molar volume VE m , viscosity deviation (Dg), refractive index deviation (DnD) and relative permittivity deviation (Der) are then calculated. All of the values of VE m and Dg are observed to be negative, while those of DnD and Der are close to zero. The effects of temperature and composition on the variation of VE m values are discussed. The negative values of VE m and Dg are conductive to high-density and lowresistance of fuels, which is favorable for the design and preparation of advanced hydrocarbon fuels.

Compounds

#	Formula	Name
1	C10H16	exo-tetrahydrodicyclopentadiene
2	C8H18	octane
3	C8H18	2,2,4-trimethylpentane
4	C8H18	3-methylheptane
5	C8H18	2,4-dimethylhexane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	5
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	1	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	5
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	2	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	5
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	3	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	5
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	4	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	5
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	5
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	5
POMD	5	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	3
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	55
POMD	2 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	55
POMD	2 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	55
POMD	2 1	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	18
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	55
POMD	4 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	55
POMD	4 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	55
POMD	4 1	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	18
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	55
POMD	5 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	55
POMD	5 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	55
POMD	5 1	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	18
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	55
POMD	3 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	55
POMD	3 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	55
POMD	3 1	Relative permittivity at various frequencies ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Frequency, MHz; Liquid	Liquid	Coaxial cylinder capacitor	18

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Excess molar volume along with viscosity, refractive index and relative permittivity for binary mixtures of exo-tetrahydrodicyclopentadiene with four octane isomers

Yue, L.[Lei], Qin, X.[Xiaomei], Wu, X.[Xi], Xu, L.[Li], Guo, Y.[Yongsheng], Fang, W.[Wenjun]

ABSTRACT