Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

Thermophysical property characterization of aqueous potassium and sodium salt solutions containing serine was conducted in this study; specifically the system s density, refractive index, electrical conductivity, and viscosity. Measurements were obtained over a temperature range of (298.15 to 343.15) K and at normal atmospheric pressure. Composition range from x1 = 0.009 to 0.07 for aqueous potassium and sodium salt solutions containing serine was used. The sensitivity of the system s thermophysical properties on temperature and composition variation were discussed and correlated based on the equations proposed for room temperature ionic liquids. The density, viscosity, and refractive index measurements of the aqueous systems were found to decrease as the temperature increases at fixed concentration and the values increase as the salt concentration increases (water composition decreases) at fixed temperature. Whereas, a different trend was observed for the electrical conductivity data; at fixed concentration, the conductivity values increase as the temperature increases and at fixed temperature, its value generally increases as the salt concentration increases but only to a certain level (specific concentration) wherein the conductivity of the solution starts to decrease when the concentration of the salt is further increased. Calculation results show that the applied models were satisfactory in representing the measured properties in the aqueous amino acid salt solution containing serine.