Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Densities, viscosities, refractive indices, and electrical conductivities of aqueous alkali salts of .alpha.-alanine

Tirona, L.-A.[Lei-An], Leron, R. B.[Rhoda B.], Soriano, A. N.[Allan N.], Li, M.-H.[Meng-Hui]
J. Chem. Thermodyn. 2014, 77, 116-122
ABSTRACT
In this work, physicochemical properties such as density, viscosity, refractive index, and electrical conductivity of aqueous alkali (potassium or sodium) salts of the amino acid a-alanine (ALA), were measured at temperatures from (303.15 to 343.15) K and concentrations ranging from (0.5 to 3.5) M. Density and viscosity measurements were performed using the vibrating tube and the falling ball techniques, respectively. The refractive index at the sodium D line was measured in an automatic refractometer, while the electrical conductivity was measured using a commercial conductivity meter. An empirical equation was applied to correlate the density, refractive index, and electrical conductivity of the amino acid salt solutions with temperature and amino acid salt concentration, which gave average absolute deviation values of 0.03%, 0.01%, and 0.6%, respectively. The variation of the viscosity as a function of temperature and amino acid salt concentration was accurately represented by a modified Vogel Tamman Fulcher equation at an average absolute deviation of 0.5%.
Compounds
# Formula Name
1 C3H6KNO2 potassium DL-alaninate
2 C3H6NNaO2 sodium DL-alaninate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 63
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 54
  • POMD
  • 3
  • 1
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 63
  • POMD
  • 3
  • 1
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 63
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 3
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 54
  • POMD
  • 3
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 54
  • POMD
  • 3
  • 2
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Alternating current cell with electrodes
  • 54