ABSTRACT

(Solid + liquid) equilibria for climbazole in various alcohols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol) were investigated. The solubility data for climbazole in pure alcohols were obtained at temperatures ranging from (278.15 to 318.15) K. The melting temperature and fusion enthalpy of climbazole were measured using a differential scanning calorimeter (TA instrument Q100) and the experimental solubility was determined by the gravimetric method. The experimental solubility data were correlated by the equation for solubility of a solid in a liquid, and the activity coefficients were estimated by a non-random two liquid (NRTL), universal quasi-chemical (UNIQUAC), and Wilson models.

Compounds

#	Formula	Name
1	C2H6O	ethanol
2	C3H8O	propan-1-ol
3	C4H10O	butan-1-ol
4	C5H12O	pentan-1-ol
5	C6H14O	hexan-1-ol
6	C7H16O	heptan-1-ol
7	C15H17ClN2O2	1-(4-Chlorophenoxy)-1-(imidazol-1-yl)-3,3-dimethylbutanone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	7	Triple point temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	7	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	1 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9
POMD	2 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9
POMD	3 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9
POMD	4 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9
POMD	5 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9
POMD	6 7	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	gravimetric	9

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Solubility of climbazole in various alcohols at different temperatures

Kim, H.[Hakmin], Lim, J.[Junhyuk], Hong, J. H.[Jung Hyun], Kim, A. R.[Ah Reum], Shin, M. S.[Moon Sam], Kim, H.[Hwayong]

ABSTRACT