Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

A comprehensive set of ternary interaction Pitzer parameters for solutions of the system Na-K-Cl-SO4-PO4-HPO4-H2PO4 was calculated from water activity and solubility data acquired from an extensive literature review and water activity data obtained from isopiestic experiments. This work is a continuation of part I, wherein results concerning binary phosphate systems are presented.

Compounds

#	Formula	Name
1	HNa2O4P	disodium hydrogen phosphate
2	H2NaO4P	sodium dihydrogen phosphate
3	HK2O4P	dipotassium hydrogen phosphate
4	H2KO4P	monopotassium phosphate
5	ClNa	sodium chloride
6	ClK	potassium chloride
7	Na2O4S	sodium sulfate
8	K2O4S	potassium sulfate
9	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2 9	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 2; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	9 3 4	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 4; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	75
POMD	1 9 3	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 3; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	1 5 9	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	75
POMD	1 9 7	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 1; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	6 9 3	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 3; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	95
POMD	9 3 8	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 3; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	2 9 4	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 2; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	48
POMD	2 9 7	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 2; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	6 9 4	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 4; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	64
POMD	9 4 8	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 4; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	75
POMD	5 9 4	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 4; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	76
POMD	9 7 3	(Relative) activity - 9 ; Liquid	Molality, mol/kg - 3; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	isopiestic method	64

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Thermodynamic modeling of high salinary phosphate solutions II. Ternary and higher systems

Scharge, T., Munoz, A. G., Moog, H. C.

ABSTRACT