Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

PVTx properties in the gas phase for binary R290/R134a system

Qi, Y.[Yingxia], Zhang, H.[Hua], Liu, Y.[Yefeng], Wu, W.[Weidong], Chen, X.[Xi], Yang, X.[Xi]
J. Chem. Thermodyn. 2014, 70, 111-121
ABSTRACT
The gaseous PVTx properties of {propane (R290) + 1,1,1,2-tetrafluoroethane (HFC-134a)} were measured at temperatures from 252 K to 320 K and corresponding pressures from 200 kPa to 2000 kPa and compositions from 0.4 to 0.65 mass fraction of R290 using the Burnett isothermal expansion method. The uncertainties in the present measurements were estimated to be within +-10 kPa for pressure, +-10 mK for temperature, and +-0.001 mass fraction for composition. On the basis of the experimental PVTx property data, the truncated virial equations of state were developed for the binary R290/R134a systems. The temperature dependences of the second and third virial coefficients are also discussed.
Compounds
# Formula Name
1 C3H8 propane
2 C2H2F4 1,1,1,2-tetrafluoroethane
3 N2 nitrogen
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 18
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 18
  • POMD
  • 3
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Burnett expansion method
  • 5
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Gas
  • Mass fraction - 1; Gas
  • Pressure, kPa; Gas
  • Temperature, K; Gas
  • Gas
  • Burnett expansion method
  • 613
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Gas
  • Temperature, K; Gas
  • Mass fraction - 1; Gas
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 101