Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Solubilities of {a-D-glucose in water + (acetic acid or propionic acid)} mixtures at atmospheric pressure and different temperatures

Li, T.[Tao], Li, Y.[Yu], Li, Y.-H.[Yan-Hong], Ren, B.-z.[Bao-zeng]
J. Chem. Thermodyn. 2013, 65, 7-10
ABSTRACT
Using dynamic method and the laser monitoring observation technique, the solubility of a-D-glucose in {water + (acetic acid or propionic acid)} was measured over the temperature range (297.55 to 331.45) K at atmospheric pressure. Its corresponding (solid + liquid) equilibrium data will provide essential support for industrial design and further theoretical studies. The solubility of a-D-glucose in the mixtures of (water + acetic acid), and (water + propionic acid) was found to increase with increasing temperature and decrease with increasing volume fractions of acetic acid, and propionic acid in aqueous solution. The experimental data were correlated by using the Apelblat equation, the kh equation and the ideal solution equation. The results showed that these three models agreed well with the experimental values, and the Apelblat equation was found to regress the solubility data better than the other two models.
Compounds
# Formula Name
1 C2H4O2 acetic acid
2 C6H12O6 .alpha.-D-glucose
3 H2O water
4 C3H6O2 propanoic acid
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitoring
  • 87
  • POMD
  • 1
  • 2
  • 3
  • Mass concentration, kg/m3 - 2 ; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitoring
  • 5
  • POMD
  • 4
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitoring
  • 83
  • POMD
  • 4
  • 2
  • 3
  • Mass concentration, kg/m3 - 2 ; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitoring
  • 4