Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

The thermodynamic properties of AOT/Dynol-604 mixed surfactant solutions

Du, C.[Changfei], Wang, H.[Huanhuan], Yin, T.[Tianxiang], Shen, W.[Weiguo]
J. Chem. Thermodyn. 2013, 64, 226-230
ABSTRACT
Volumetric properties of mixed surfactants of Bis(2-ethylhexyl) sodium sulfosuccinate (AOT) and Ethoxylated- 2,5,8,11-tetramethyl-6-dodecyne-5,8-diol (Dynol-604) in aqueous solutions with various compositions have been studied at 298.15 K by density measurements. The apparent molar volumes, the partial molar volumes, the critical micelle concentrations, and the apparent molar volumes in the monomeric and micellar states of the binary mixed surfactants with various compositions were determined. Moreover, the results were used to calculate the micellar compositions, the excess free energies of mixing, the activity coefficients and the interaction parameter between two surfactants for the mixed micelles based on the Rubingh's formulism
Compounds
# Formula Name
1 C20H37NaO7S sodium bis(2-ethylhexyl) sulfosuccinate
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 16