ABSTRACT

Experimental isothermal (P-x) data at T = 313.15 K for the binary (1-butanol + 1-hexene) and ternary (1- butanol + 2,2,4-trimethylpentane + 1-hexene) systems are reported. The measurements have been performed with an isothermal total pressure cell. Data reduction by Barker s method provides correlations for GE, using the Margules equation for the binary system and the Wohl expansion for the ternary system. Wilson, NRTL, and UNIQUAC models have been applied successfully to the data correlation of the binary and ternary systems. The mixtures investigated exhibit positive deviation from ideal behaviour. Good results are obtained for the correlation by all the models.

Compounds

#	Formula	Name
1	C4H10O	butan-1-ol
2	C6H12	hex-1-ene
3	C8H18	2,2,4-trimethylpentane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	1 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	28
POMD	1 3 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	78
POMD	1 3	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	2
POMD	3 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	2

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Vapour-liquid equilibria of binary and ternary mixtures containing 1-butanol, 2,2,4-trimethylpentane and 1-hexene at T = 313.15 K

Ghellai, S.[Saadya], Belabbaci, A.[Aouicha], Villamanan, R. M.[Rosa M.], Martin, M. C., Villamanan, M. A.[Miguel A.], Negadi, L.[Latifa]

ABSTRACT