ABSTRACT

Tri(1-ethyl-3-methylimidazolium) gadolinium hexachloride ([emim]3[GdCl6]), tri(1-butyl-3-methylimidazolium) hexagadolinium chloride ([bmim]3[GdCl6]), di(tetramethylammonium) manganese tetrachloride ([TMA]2[MnCl4]) and cholinium tetrachloroferrate ([Chol][FeCl4]) were synthetized and their solubility in water, ethanol, 1-propanol and 1-butanol were determined as a function of temperature. Activity coefficients were calculated and their comparison with ideal solutions is discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation. In addition, melting point depression effect of high pressure carbon dioxide was studied.

Compounds

#	Formula	Name
1	C18H33Cl6GdN6	tri(1-ethyl-3-methylimidazolium) gadolinium hexachloride
2	C24H45Cl6GdN6	tri(1-butyl-3-methylimidazolium) gadolinium hexachloride
3	C8H24Cl4MnN2	bis(tetramethylammonium) tetachloromanganate
4	C5H14Cl4FeNO	cholinium tetrachloroferrate
5	C2H6O	ethanol
6	C3H8O	propan-1-ol
7	C4H10O	butan-1-ol
8	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	1	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	2	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	2	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	4	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	4	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	8 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Visual Dynamic Method	8
POMD	5 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Visual Dynamic Method	8
POMD	6 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Visual Dynamic Method	10
POMD	7 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Visual Dynamic Method	8
POMD	5 3	Mole fraction - 3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 3	Visual Dynamic Method	4
POMD	6 3	Mole fraction - 3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 3	Visual Dynamic Method	2
POMD	5 4	Mole fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Visual Dynamic Method	10
POMD	6 4	Mole fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Visual Dynamic Method	16
POMD	7 4	Mole fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Visual Dynamic Method	15

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Solubility and phase behavior of binary systems containing salts based on transitional metals

Zakrzewska, M. E.[Malgorzata E.], Paninho, A. B.[Ana B.], Molho, M. F.[Marta F.], Nunes, A. V. M.[Ana V.M.], Afonso, C. A. M.[Carlos A.M.], Rosatella, A. A.[Andreia A.], Lopes, J. M.[Joana M.], Najdanovic-Visak, V.[Vesna]

ABSTRACT