Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Diffusion of cadmium chloride in aqueous solutions at physiological temperature 310.15 K

Ribeiro, A. C. F.[Ana C.F.], Gomes, J. C. S.[Joselaine C.S.], Verissimo, L. M. P.[Luis M.P.], Romero, C.[Carmen], Blanco, L. H.[Luis H.], Esteso, M. A.[Miguel A.]
J. Chem. Thermodyn. 2013, 57, 404-407
ABSTRACT
Mutual diffusion coefficients (interdiffusion coefficients) of cadmium (II) chloride in water at T = 310.15 K at concentrations between 0.001 mol dm 3 and 0.400 mol dm 3 have been determined, using the Taylor technique. The results are discussed on the basis of Nernst, and Onsager and Fuoss theories, taking into account different phenomena such as electrophoretic and thermodynamic effects. Using such results, the equivalent conductance at infinitesimal concentration of the cadmium (II) ion in these solutions at T = 310.15 K has been estimated. These results permit us to have a better understanding of the structure of the cited systems and the thermodynamic behaviour of cadmium chloride in aqueous solutions.
Compounds
# Formula Name
1 CdCl2 cadmium chloride
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Binary diffusion coefficient, m2/s ; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Taylor dispersion method
  • 9