Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Henry s constants and activity coefficients of some organic solutes in 1-butyl,3-methylimidazolium hydrogen sulfate and in 1-methyl,3-trimethylsilylmethylimidazolium chloride

Yoo, B.[Brian], Afzal, A.[Waheed], Prausnitz, J. M.[John M.]
J. Chem. Thermodyn. 2013, 57, 178-181
ABSTRACT
Using a customized capillary gas liquid chromatography column, Henry s constants and activity coefficients at infinite dilution are reported for benzene, toluene, ethyl acetate, 1,4-dioxane, 1,2-dimethoxyethane, acetonitrile, nitromethane, tetrahydrofuran, chloroform, methanol, ethanol, and 1-propanol in ionic liquids 1-butyl,3-methylimidazolium hydrogen sulfate [BMIM][HSO4] and 1-methyl,3-trimethylsilylmethylimidazolium [SiMIM][Cl] chloride from 313 to 413 K. These acidic ionic liquids may provide suitable media for acid-catalyzed chemical reactions.
Compounds
# Formula Name
1 C6H6 benzene
2 C7H8 toluene
3 C4H8O2 ethyl acetate
4 C4H8O2 1,4-dioxane
5 C4H10O2 1,2-dimethoxyethane
6 C2H3N acetonitrile
7 CH3NO2 nitromethane
8 C4H8O tetrahydrofuran
9 CHCl3 trichloromethane
10 CH4O methanol
11 C2H6O ethanol
12 C3H8O propan-1-ol
13 C8H16N2O4S 1-butyl-3-methylimidazolium hydrogen sulfate
14 C8H17ClN2Si 1-methyl-3-(trimethylsilylmethyl)imidazolium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 13
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:mpoint
  • 13
  • POMD
  • 14
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:mpoint
  • 11
  • POMD
  • 1
  • 13
  • Activity coefficient - 1 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 2
  • 13
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 3
  • 13
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 4
  • 13
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 5
  • 13
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 6
  • 13
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 7
  • 13
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 8
  • 13
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 1
  • 14
  • Activity coefficient - 1 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 2
  • 14
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 3
  • 14
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 4
  • 14
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 5
  • 14
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 6
  • 14
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 7
  • 14
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 8
  • 14
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 9
  • 14
  • Activity coefficient - 9 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 10
  • 14
  • Activity coefficient - 10 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 3
  • POMD
  • 11
  • 14
  • Activity coefficient - 11 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 11; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 3
  • POMD
  • 12
  • 14
  • Activity coefficient - 12 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 3