Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric properties of binary mixtures of dimethyl sulfoxide with amines from (293.15 to 363.15) K

Wang, X.[Xiaopo], Yang, F.[Fuxin], Gao, Y.[Yuan], Liu, Z.[Zhigang]
J. Chem. Thermodyn. 2013, 57, 145-151
ABSTRACT
The new densities of binary mixtures of dimethyl sulfoxide (DMSO) with primary, secondary, and tertiary amines {2-aminoethanol (MEA), 2,20-iminodiethanol (DEA), and bis(2-hydroxyethyl)methylamine (MDEA)} were measured at the atmospheric pressure for the temperatures ranging from (293.15 to 363.15) K over the entire composition range using an Anton Paar digital vibrating U-tube densimeter (model DMA 5000 M). A Redlich Kister type equation was correlated using the excess molar volumes calculated with the experimental values and used to represent the densities of the liquid mixtures as a function of temperature and concentration. The thermal expansion coefficients of the pure components along with their binary mixtures using the experimental data are represented and discussed.
Compounds
# Formula Name
1 C2H7NO 2-aminoethan-1-ol
2 C4H11NO2 diethanolamine
3 C5H13NO2 N-methyldiethanolamine
4 C2H6OS dimethyl sulfoxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 88
  • POMD
  • 4
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 88
  • POMD
  • 4
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 88