ABSTRACT

Recommended vapor pressure data for ferrocene (CAS Registry Number: 102-54-5) in the temperature range from 242 K to 447 K were developed by the simultaneous correlation of critically assessed vapor pressures, heat capacities of the crystalline phase and the ideal gas, and calorimetrically determined enthalpies of sublimation. All of the properties needed for the correlation were newly determined in this work. The value for the enthalpy of sublimation, Dg crHm(298.15 K) = (74.38 +- 0.38) kJ mol 1, is recommended. Comparisons with literature values are shown for all measured and derived properties.

Compounds

#	Formula	Name
1	C10H10Fe	ferrocene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	1	Vapor or sublimation pressure, kPa ; Crystal	Temperature, K; Crystal		Crystal Gas	Closed cell (Static) method	69
POMD	1	Vapor or sublimation pressure, kPa ; Crystal	Temperature, K; Crystal		Crystal Gas	Closed cell (Static) method	39
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Closed cell (Static) method	3
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Crystal	Temperature, K; Crystal	Pressure, kPa; Crystal	Crystal	Step	17
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Crystal	Temperature, K; Crystal Pressure, kPa; Crystal		Crystal	Drop calorimetry	1
POMD	1	Solid-liquid equilibrium temperature, K ; Crystal	Pressure, kPa; Crystal		Crystal Liquid	DTA	1

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Recommended vapor pressure and thermophysical data for ferrocene

Fulem, M.[Michal], Ruzicka, K.[Kvetoslav], Cervinka, C.[Ctirad], Rocha, M. A. A.[Marisa A.A.], Santos, L. M. N. B. F.[Luis M. N. B. F.], Berg, R. F.[Robert F]

ABSTRACT