Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental and computational thermochemistry of 6,7-dihydro-4(5H)-benzofuranone

Sousa, C. C. S.[Clara C.S.], Morais, V. M. F.[Victor M. F.], Matos, M. A. R.[M. Agostinha R.]
J. Chem. Thermodyn. 2013, 56, 83-88
ABSTRACT
The standard (p = 0.1 MPa) molar enthalpy of formation of 6,7-dihydro-4(5H)-benzofuranone was measured, at T = 298.15 K, by static bomb calorimetry and the standard molar enthalpy of vaporization, at T = 298.15 K, was obtained using Calvet microcalorimetry. These values were combined together to derive the standard molar enthalpy of formation of the title compound in gaseous phase, at T = 298.15 K, (226.0 +- 2.8) kJ mol-1.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 H2O water
3 O2 oxygen
4 H2 hydrogen
5 C graphite
6 C8H8O2 6,7-dihydrobenzofuran-4(5H)-one
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 6
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • drop calorimetry
  • 1
  • RXND
  • 6
  • 1
  • 2
  • 3
  • Specific internal energy of reaction at constant volume, J/g
  • Static bomb calorimetry
  • 1
  • RXND
  • 6
  • 4
  • 5
  • 3
  • Molar enthalpy of reaction, kJ/mol
  • Static bomb calorimetry
  • 1
  • RXND
  • 6
  • 4
  • 5
  • 3
  • Molar enthalpy of reaction, kJ/mol
  • Static bomb calorimetry
  • 1