Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Effect of hydrolysis on the diffusion of ferric sulphate in aqueous solutions at T = 298.15 K

Verissimo, L. M. P.[Luis M. P.], Ribeiro, A. C. F.[Ana C. F.], Lobo, V. M. M.[Victor M. M.], Esteso, M. A.[Miguel A.]
J. Chem. Thermodyn. 2012, 55, 56-59
ABSTRACT
Diffusion coefficients of the Fe2(SO4)3)/water system at T = 298.15 K and at concentrations between 0.050 mol dm 3 and 0.200 mol dm 3 have been measured, using a conductimetric cell and an automatic apparatus to follow diffusion. The cell uses an open-ended capillary method. A conductimetric technique is used to follow the diffusion process by measuring the resistance of a solution inside the capillaries at recorded times. These data are discussed on the basis of the Onsager Fuoss model. The diffusion of Fe2(SO4)3 is clearly affected by the Fe (III) hydrolysis. These data permit us to have a better understanding of the structure of such systems and the thermodynamic behaviour of ferric sulphate in different media.
Compounds
# Formula Name
1 Fe2O12S3 ferric sulfate
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Binary diffusion coefficient, m2/s ; Liquid
  • Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Open capillary
  • 6